• 专利标题:   Preparing reverse osmosis membrane modified by graphene oxide/polyvinyl alcohol coating, involves mixing m-phenylenediamine, triethylamine and camphorsulfonic acid to obtain aqueous solution, and mixing trimesoyl chloride in oil.
  • 专利号:   CN107638805-A
  • 发明人:  
  • 专利权人:   NINGBO RIXIN HENGLI TECHNOLOGY CO LTD
  • 国际专利分类:   B01D061/02, B01D067/00, B01D071/56, C02F001/44
  • 专利详细信息:   CN107638805-A 30 Jan 2018 B01D-061/02 201820 Chinese
  • 申请详细信息:   CN107638805-A CN11076072 03 Nov 2017
  • 优先权号:   CN11076072

▎ 摘  要

NOVELTY - Preparing reverse osmosis membrane modified by graphene oxide/polyvinyl alcohol coating, involves mixing 3-8% m-phenylenediamine, 2-6% triethylamine and 5-10% camphorsulfonic acid to obtain aqueous solution, and mixing 0.1-0.5% trimesoyl chloride in oil to obtain oil phase solution. The polysulfone support film is affixed to the aqueous solution by affixing to a stainless steel sheet. The solvent is removed, and the interfacial polymerization reaction is carried out by immersing in the oil phase solution. The solvent is removed to obtain a preliminary ecological reverse osmosis membran. USE - Method used for preparing reverse osmosis membrane (claimed). ADVANTAGE - The method ensures improved polyvinyl alcohol coat modified reverse osmosis membrane water flux decline, and thus polyvinyl alcohol coating is easy to fall off. DETAILED DESCRIPTION - Preparing reverse osmosis membrane modified by graphene oxide/polyvinyl alcohol coating, involves mixing 3-8% m-phenylenediamine, 2-6% triethylamine and 5-10% camphorsulfonic acid to obtain aqueous solution, and mixing 0.1-0.5% trimesoyl chloride in oil to obtain oil phase solution. The polysulfone support film is affixed to the aqueous solution by affixing to a stainless steel sheet. The solvent is removed, and the interfacial polymerization reaction is carried out by immersing in the oil phase solution. The solvent is removed to obtain a preliminary ecological reverse osmosis membran. The cross-linking reaction solution of polyvinyl alcohol containing graphene oxide A mixture of graphene oxide aqueous solution and polyvinyl alcohol aqueous solution is mixed, and magnetically stirred for 5-10 minutes, ultrasonically dispersed for 30-60 minutes, and then cross-linking agent, serine, and acid are added. The catalyst obtains a polyvinyl alcohol crosslinking reaction solution containing graphene oxide. The graphene oxide-containing polyvinyl alcohol cross-linking reaction solution is coated on the surface of the preliminary ecological reverse osmosis membrane, and placed in an oven at 60-120 degrees C temperature for 5-20 minutes to obtain graphene oxide/polyvinyl alcohol coating modified reverse osmosis membrane.