• 专利标题:   Low-temperature chemical vapor deposition preparation of graphene strip by inserting polished electrolytic copper foil and copper plate into polishing solution, drying with nitrogen, passing hydrogen and liquid carbon and growing graphene.
  • 专利号:   CN103086370-A
  • 发明人:   LIU C, ZHANG Y, ZHANG B
  • 专利权人:   UNIV NORTHEASTERN CN
  • 国际专利分类:   B82Y040/00, C01B031/04
  • 专利详细信息:   CN103086370-A 08 May 2013 C01B-031/04 201373 Pages: 7 Chinese
  • 申请详细信息:   CN103086370-A CN10021420 22 Jan 2013
  • 优先权号:   CN10021420

▎ 摘  要

NOVELTY - Low-temperature chemical vapor deposition preparation of graphene strip includes polishing electrolytic copper foil as anode, copper plate as cathode, inserting electrodes into polishing solution, electrifying, drying with nitrogen; annealing copper foil in quartz tube reactor and horizontal heating furnace constant-temperature area, evacuating inner wall of quartz tube reactor, passing hydrogen, heating furnace; annealing, adjusting hydrogen flow rate, passing liquid carbon, growing graphene into copper foil strips, controlling pressure and growth time; and cooling to room temperature. USE - Method for preparing graphene strip adopting low-temperature chemical vapor deposition (claimed). ADVANTAGE - The surface of copper foil has high chemical activity. DETAILED DESCRIPTION - Low-temperature chemical vapor deposition preparation of graphene strip comprises polishing electrolytic copper foil as anode and copper plate as cathode, simultaneously inserting two electrodes into polishing solution, electrifying at constant current of 1-1.5 A for 70-120 seconds, drying with nitrogen, setting aside; annealing copper foil in quartz tube reactor and horizontal heating furnace constant-temperature area, where one end of quartz tube reactor is connected to hydrogen bottle and liquid carbon container and other end connected to vacuum pump, evacuating inner wall of quartz tube reactor to 10-2 torr, passing hydrogen at 4-10 standard cubic centimeter/minute (sccm), heating furnace at 5-50 degrees C/minute, heating to 500-950 degrees C for 30-60 minutes; annealing at 500-580 degrees C, adjusting hydrogen flow rate to 2.4-3 sccm, passing liquid carbon, growing graphene into copper foil strips, controlling pressure at 2-10 torr and controlling growth time for 10-50 minutes; and cooling to room temperature. The said electrolytic polishing solution is obtained by mixing uniformly 1000 ml deionized water, 500 ml phosphoric acid, 500 ml ethanol, 100 ml isopropanol and 9 g urea.