• 专利标题:   High thermal conductivity flame retardant graphene flexible film useful for electronic device heat dissipating material, obtained by introducing flame retardant reducing agent into surface of graphene oxide sheet by functionalization.
  • 专利号:   CN108192577-A
  • 发明人:   WU K, LIU Y, LUO F, LIANG L, SHI J, LV M
  • 专利权人:   CHINESE ACAD SCI GUANGZHOU CHEM RES INST, CAS GUANGZHOU CHEM CO LTD NANXIONG MATER, SHAOGUAN TECH INNOVATION INCUBATION CE, NANXIONG CAS INCUBATOR OPERATION CO LTD, UNIV CHINESE ACAD SCI
  • 国际专利分类:   C09K005/14, C09K021/06, C09K021/04, C09K021/02
  • 专利详细信息:   CN108192577-A 22 Jun 2018 C09K-005/14 201848 Pages: 5 Chinese
  • 申请详细信息:   CN108192577-A CN11485232 29 Dec 2017
  • 优先权号:   CN11485232

▎ 摘  要

NOVELTY - High thermal conductivity flame retardant graphene flexible film, obtained by introducing a flame retardant reducing agent into surface of the graphene oxide sheet by functionalization or grafting, reducing the graphene oxide, and adding a filler to form a film, the mass ratio of flame retardant reducing agent and graphene oxide is 1:1-10, and flame retardant reducing agent and filler is 1-1.2:1. USE - The flexible film is useful for electronic device heat dissipating material (claimed). ADVANTAGE - The film has thermal conductivity of 15W/m/K in plane direction and vertical surface reaches to 0.8W/m/K, tensile strength is 35Mpa, good flame retardant performance, does not release heat below 500 degrees C, where peak heat release is 37 W/g or less at highest heat release temperature of 540 degrees C. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing high thermal conductivity flame retardant graphene flexible film, comprising (i) adding a flame retardant reducing agent into aqueous graphene oxide dispersion, adjusting pH to 8-10, processing ultrasonically for 30-90 minutes, stirring and dispersing at 50-90 degrees C; (ii) adding filler and dispersing ultrasonically for 30-90 minutes; and (iii) volatilizing the solvent, and drying.