• 专利标题:   Producing hexafluorobutadiene involves mixing adsorption resin, aqueous oxidized graphene solution, potassium borohydride and water, and then filtering the mixed solution to obtain filtrate.
  • 专利号:   CN106349008-A, CN106349008-B
  • 发明人:   CHEN G, ZHANG X, ZHOU J, LI J, ZHANG G, WANG N, CHEN L, QIAN H, HUA Y, ZHENG J
  • 专利权人:   ZHEJIANG BORUI ELECTRONIC TECHNOLOGY CO
  • 国际专利分类:   B01J020/26, C07C017/38, C07C017/389, C07C021/20
  • 专利详细信息:   CN106349008-A 25 Jan 2017 C07C-017/38 201722 Pages: 6 Chinese
  • 申请详细信息:   CN106349008-A CN10567156 19 Jul 2016
  • 优先权号:   CN10567156

▎ 摘  要

NOVELTY - Producing hexafluorobutadiene involves mixing adsorption resin, aqueous oxidized graphene solution, potassium borohydride and water in weight ratio of 100:2-10:0.05-0.5:300-1000 at 50-100 degrees C for 30-80 hours, and then filtering the mixed solution to obtain filtrate. The specific surface area of adsorption resin is 500-1000m2/g. The filtrate is dried in presence of nitrogen, and then calcined at 200-400 degrees C for 1-3 hours. The obtained product is roasted at 500-800 degrees C for 1-5 hours, and further roasted at 900-1200 degrees C for 1-5 hours. USE - Method for producing hexafluorobutadiene (claimed). ADVANTAGE - The method enables to produce hexafluorobutadiene with high purity. DETAILED DESCRIPTION - Producing hexafluorobutadiene involves mixing adsorption resin, aqueous oxidized graphene solution, potassium borohydride and water in weight ratio of 100:2-10:0.05-0.5:300-1000 at 50-100 degrees C for 30-80 hours, and then filtering the mixed solution to obtain filtrate. The specific surface area of adsorption resin is 500-1000m2/g. The filtrate is dried in presence of nitrogen, and then calcined at 200-400 degrees C for 1-3 hours. The obtained product is roasted at 500-800 degrees C for 1-5 hours, and further roasted at 900-1200 degrees C for 1-5 hours. The roasted product is cooled to room temperature to get efficient adsorbent. The efficient adsorbent is processed in an adsorption tower at 0-30 degrees C and 0.1-1MPa. The vacuum distillation of obtained product is carried out to remove impurities to obtain the final product i.e. hexafluorobutadiene.