• 专利标题:   Preparing salicylaldehyde Schiff base/graphene oxide modified paper-based material for detecting copper ions, by refluxing salicylaldehyde and 1,2,4,5-benzenetetramine hydrochloride and soaking graphene oxide-modified paper in Schiff base.
  • 专利号:   CN110565440-A
  • 发明人:   ZHANG S, FAN J, DU M, HE B, YAO X, LIU Y
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   C07C249/02, D21H017/00, D21H017/06, D21H017/07, D21H027/00, G01N021/64, G01N021/78
  • 专利详细信息:   CN110565440-A 13 Dec 2019 D21H-027/00 201999 Pages: 8 Chinese
  • 申请详细信息:   CN110565440-A CN10844388 06 Sep 2019
  • 优先权号:   CN10844388

▎ 摘  要

NOVELTY - Method for preparing salicylaldehyde Schiff base/graphene oxide modified paper-based material, involves (a) refluxing salicylaldehyde and 1,2,4,5-benzenetetramine hydrochloride in a mass ratio of (30-90):(10-30), separating the product in the reaction solution, drying to obtain salicylaldehyde Schiff base, soaking a paper in a graphene oxide dispersion, and drying to obtain a graphene oxide-modified paper-based material, (b) soaking the graphene oxide-modified paper-based material in salicylaldehyde Schiff base solution, and compounding the graphene oxide and salicylaldehyde Schiff base on the paper to form a composite (A), and (c) taking out the composite (A), drying to obtain the salicylaldehyde Schiff base/graphene oxide modified paper-based material. USE - The method is useful for preparing salicylaldehyde Schiff base/graphene oxide modified paper-based material used for detecting cupric ions in water (all claimed). ADVANTAGE - The prepared paper-based material achieves rapid detection of cupric through electrostatic interaction and coordination chelation between the hydroxyl, carboxyl and carbon-nitrogen double bonds in the material and cupric ions.