• 专利标题:   Manufacture of graphene-based nano-metal compound array material used as e.g. battery material, involves mixing carbon precursor and metal salt containing zinc chloride, coating resultant on nickel substrate, electrodepositing and heating.
  • 专利号:   CN106914244-A
  • 发明人:   ZHU J, ZHANG Y, HUANG W
  • 专利权人:   UNIV NANJING TECHNOLOGY
  • 国际专利分类:   B01J023/745, B01J023/75, B01J023/755, B01J027/24, C25B011/06, H01M004/62
  • 专利详细信息:   CN106914244-A 04 Jul 2017 B01J-023/745 201768 Pages: 11 Chinese
  • 申请详细信息:   CN106914244-A CN10127812 06 Mar 2017
  • 优先权号:   CN10127812

▎ 摘  要

NOVELTY - Manufacture of graphene-based nano-metal compound array material involves mixing a carbon precursor and a metal salt comprising potassium chloride and zinc chloride, grinding, coating resultant slurry on a foamed nickel substrate, heat-treating, washing, obtaining graphite-carbon nanosheets, subjecting resultant to electrodeposition using a dilute nitrate solution at room temperature, obtaining graphite-based metal hydroxide, and heat-treating. The carbon precursor is a mixture of glucose, and melamine or 1-ethyl-3-methylimidazolium dicyandiamide. USE - Manufacture of graphene-based nano-metal compound array material used as battery material for metal-ion battery, metal-air battery and supercapacitor, and material for electrocatalytic reaction, oxidation-reduction reaction, and precipitation reaction (all claimed). ADVANTAGE - The method enables simple and non-toxic manufacture of graphene-based nano-metal compound array material having excellent conductivity, ion-transport property, stability, electrochemical catalytic activity and durability. DETAILED DESCRIPTION - Manufacture of graphene-based nano-metal compound array material involves mixing a carbon precursor and a metal salt comprising potassium chloride and zinc chloride, grinding, coating resultant slurry on a foamed nickel substrate, heat-treating resultant product in an inert atmosphere at 700-100 degrees C for 0.5 hour or more, washing using deionized water and ethanol, respectively, obtaining graphite-carbon nanosheets, subjecting resultant to electrodeposition using a dilute nitrate solution at room temperature for 6-60 hours, obtaining graphite-based metal hydroxide, and heat-treating resultant at 500 degrees C or less and heating rate of 2-15 degrees C/minute for 1-5 hours. The carbon precursor is a mixture of glucose, and melamine or 1-ethyl-3-methylimidazolium dicyandiamide.