• 专利标题:   Preparation of modified MFI-type molecular sieve by dissolving graphene in deionized water, adding ammonia water to adjust pH, and ultrasonically dispersing to form brown sol suspension until there is no graphene particles.
  • 专利号:   CN110759355-A
  • 发明人:   ZHANG L, CHANG X, CHANG Y
  • 专利权人:   UNIV LIAONING SHIHUA
  • 国际专利分类:   B01J029/40, C01B039/40
  • 专利详细信息:   CN110759355-A 07 Feb 2020 C01B-039/40 202016 Pages: 8 Chinese
  • 申请详细信息:   CN110759355-A CN11027413 28 Oct 2019
  • 优先权号:   CN11027413

▎ 摘  要

NOVELTY - Preparation of modified MFI-type molecular sieve, where molecular sieve is ZSM-5, comprises taking graphene, dissolving in 1-2 L deionized water, adding ammonia water to adjust pH of the solution at 7-8, ultrasonically dispersing with an ultrasonic cleaner to form brown sol suspension until there is no graphene particles to obtain graphene suspension, mixing silicon source, aluminum source, tetrapropylammonium hydroxide (TPAOH) and distilled water by stirring at room temperature, adding graphene suspension, mixing uniformly to obtain crystal gel precursor, where the mass ratio of graphene and silicon source is 1-10 mass%, placing in a hydrothermal reaction kettle, under crystallization temperature, conducting crystallization reaction to obtain crystallized product, centrifuging, washing,drying and roasting. USE - The method is for preparation of modified MFI-type molecular sieve. ADVANTAGE - The method improves the diffusion property of porous ZSM-5 molecular sieve.