• 专利标题:   Preparing graphene wave-absorbing patch by adding boron-containing dopant to graphite oxide solution, heating, washing, filtering, freeze-drying, adding ethanol, centrifuging, adding tetrahydrofuran and plasticizer, heating and drying.
  • 专利号:   CN110760081-A
  • 发明人:   TAN L, ZHANG X, PENG S
  • 专利权人:   GANSU WEINA TECHNOLOGY CO LTD
  • 国际专利分类:   C08J005/18, C08K003/04, C08K005/053, C08K009/02, C08L001/28, C08L067/04, C08L071/02, H05K009/00
  • 专利详细信息:   CN110760081-A 07 Feb 2020 C08J-005/18 202018 Pages: 17 Chinese
  • 申请详细信息:   CN110760081-A CN11006767 22 Oct 2019
  • 优先权号:   CN11006767

▎ 摘  要

NOVELTY - Method for preparing graphene wave-absorbing patch by (i) adding boron-containing dopant to graphite oxide solution, hydrothermally heating and performing constant heat reaction to obtain black gel-like liquid, (ii) cooling the black gel-like liquid to room temperature, washing and filtering with deionized water and freeze-drying, (iii) adding absolute ethanol to boron-doped graphene powder to obtain dispersion, and centrifuging to obtain a supernatant, (iv) adding supernatant and tetrahydrofuran to polylactic acid, stirring and dissolving the mixture to obtain a mixed solution, adding plasticizer to the mixed solution, mixing to obtain polylactic acid-boron-doped graphene mixed solution, and (v) heating polylactic acid-boron-doped graphene mixed solution in stainless steel reactor to obtain polylactic acid-boron-doped graphene casting film solution, taking out and pouring the casting film solution into steel sheet or petri dish and natural drying. USE - Method for preparing graphene wave-absorbing patch. ADVANTAGE - The method is economical, simple and consumes less energy. DETAILED DESCRIPTION - Method for preparing graphene wave-absorbing patch by (i) adding boron-containing dopant to graphite oxide solution in a ratio of (1-3):(100-200) g/ml, hydrothermally heating at 120 degrees C, and continuously performing constant heat reaction for 1-3 hours to obtain black gel-like liquid, (ii) cooling the black gel-like liquid to room temperature, washing and filtering several times with deionized water and freeze-drying to obtain black boron-doped graphene powder, (iii) adding absolute ethanol to boron-doped graphene powder to obtain dispersion having a concentration of 2-5 mg/ml, and centrifuging to obtain a supernatant, (iv) sequentially adding supernatant and tetrahydrofuran to polylactic acid, stirring and dissolving the mixture to room temperature to obtain a mixed solution, adding 5-30 %mass plasticizer to the mixed solution, uniformly mixing to obtain polylactic acid-boron-doped graphene mixed solution, where the ratio of polylactic acid to supernatant is 1:20 g/ml, and polylactic acid to tetrahydrofuran is 1:20 g/ml and (v) hydrothermally heating polylactic acid-boron-doped graphene mixed solution at 100 degrees C stainless steel reactor for 30 minutes to obtain polylactic acid-boron-doped graphene casting film solution, quickly taking out and pouring the casting film solution into steel sheet or petri dish and natural drying to obtain the product.