• 专利标题:   Resin based transition metal building material comprises zirconium oxychloride, nickel (II) chloride, graphene oxide, styrene, dibenzoyl peroxide, polystyrene, alkyd resin, calcium propionate, and tetrahydrofurfuryl alcohol.
  • 专利号:   CN106832630-A
  • 发明人:   JIANG H
  • 专利权人:   JIANG H
  • 国际专利分类:   C08K013/06, C08K003/04, C08K009/04, C08K009/12, C08L025/06, C08L067/08
  • 专利详细信息:   CN106832630-A 13 Jun 2017 C08L-025/06 201750 Pages: 6 Chinese
  • 申请详细信息:   CN106832630-A CN11164698 16 Dec 2016
  • 优先权号:   CN11164698

▎ 摘  要

NOVELTY - Resin based transition metal building material comprises comprises 6-8 pts. wt. zirconium oxychloride, 7-9 pts. wt. nickel (II) chloride, 10-14 pts. wt. graphene oxide, 20-30 pts. wt. styrene, 0.1-0.2 pts. wt. dibenzoyl peroxide, 100-110 pts. wt. polystyrene, 3-4 pts. wt. alkyd resin, 1-2 pts. wt. calcium propionate, 1-2 pts. wt. tetrahydrofurfuryl alcohol, 0.4-1 pts. wt. saturated octadecanamide, 0.8-1 pts. wt. p butylphenol, 1-2 pts. wt. carboxylic acid glyceride, 0.01-0.02 pts. wt. dibasic lead phosphite, 6-8 pts. wt. potassium silicate, and 1-2 pts. wt. pyromellitic dianhydride. USE - Resin based transition metal building material. ADVANTAGE - The resin based transition metal building material effectively improves the filler dispersibility in the polymer to improve stability strength of finished product, and the final material has good heat retaining property, high impact strength and excellent comprehensive performance. DETAILED DESCRIPTION - Resin based transition metal building material comprises 6-8 pts. wt. zirconium oxychloride, 7-9 pts. wt. nickel (II) chloride, 10-14 pts. wt. graphene oxide, 20-30 pts. wt. styrene, 0.1-0.2 pts. wt. dibenzoyl peroxide, 100-110 pts. wt. polystyrene, 3-4 pts. wt. alkyd resin, 1-2 pts. wt. calcium propionate, 1-2 pts. wt. tetrahydrofurfuryl alcohol, 0.4-1 pts. wt. saturated octadecanamide, 0.8-1 pts. wt. p butylphenol, 1-2 pts. wt. carboxylic acid glyceride, 0.01-0.02 pts. wt. dibasic lead phosphite, 6-8 pts. wt. potassium silicate, 1-2 pts. wt. pyromellitic dianhydride, 0.1-0.2 pts. wt. sulfuric acid having concentartion of 90-95% and 5-7 pts. wt. montmorillonite powder. An INDEPENDENT CLAIM is included for a method for producing resin based transition metal building material, which involves: (A) adding pyromellitic dianhydride into 17-20 times of deionized water, stirring uniformly, raising temperature at 60-65 degrees C for 4-10 minutes, adding potassium silicate, sulfuric acid, and montmorillonite powder, stirring the reaction for 30-40 minutes, filtering and washing the sediment for 3-4 times, drying at room temperature to obtain modified stone powder; (B) mixing the graphene oxide and modified stone powder into 200-300 times of deionized water, and sonicating for 100-120 minutes to obtain a graphene dispersion; (C) adding p butylphenol to 10-14 times by weight of absolute ethanol, stirring and adding tetrahydrofurfuryl alcohol and alkyd resin at 70-75 degrees C, for 20-30 minutes, adding dibasic lead phosphite, and stirring to room temperature, to get alcohol dispersion; (D) mixing zirconium oxychloride and nickel chloride and adding to deionized water having a weight of 70-100 times of the mixture, stirring uniformly, and mixing with graphene dispersion, stirring and feed into a reaction vessel, dropping ammonia having concentration of 10-14%, adjusting the pH of 10-11, at 190-200 degrees C, for 6-7 hours to get material, washing the material 2-3 times and drying at 76-80 degrees C for 20-25 hours to pre-treated graphene; (E) adding pretreated graphene to the dimethylformamide having weight of 100-110 times, for 1-2 hours to obtain amide dispersion; (F) adding styrene to dimethylformamide having a weight of 17-20 times and stirring for 16 to 20 minutes, mixing mixture was with amide dispersion, stirring uniformly, and adding dibenzoyl peroxide, stirring at 70-75 degrees C for 1-2 hours, placing mixture in the oven, drying at 120-130 degrees C, cooling the material to obtain polymer modified graphene; (G) adding polystyrene to the alcohol dispersion, stirring, adding saturated octadecanamide at 40-50 degrees C for 7-10 minutes to obtain amide alcohol dispersion; and (H) mixing polymer modified graphene and amide alcohol dispersions and stirring uniformly, adding remaining raw materials, and feeding into internal mixer, raising the temperature at 180-190 degrees C, heating for 10-12 minutes, cooling to room temperature, putting mixture into flat vulcanizing machine, at 190-200 degrees C, under pressure of 10-15 megapascal for 3-4 minutes, cooling, and grinding to get fine powder.