• 专利标题:   Composite modified diaphragm for lithium-sulfur battery, has modified layer laid on one side of diaphragm base and modified layer including at least two carbon nanotubes layers and at least one cerium oxide/carbon/reduced graphene oxide.
  • 专利号:   CN111969164-A
  • 发明人:   LIU J, WU Y, WU D, ZHANG Q, YAN J
  • 专利权人:   UNIV HEFEI TECHNOLOGY
  • 国际专利分类:   H01M010/052, H01M002/14, H01M002/16
  • 专利详细信息:   CN111969164-A 20 Nov 2020 H01M-002/16 202000 Pages: 13 Chinese
  • 申请详细信息:   CN111969164-A CN10988830 18 Sep 2020
  • 优先权号:   CN10988830

▎ 摘  要

NOVELTY - Composite modified diaphragm for lithium-sulfur battery, comprises a diaphragm substrate and a modified layer laid on one side of the diaphragm base. The diaphragm substrate is a common commercial battery diaphragm substrate. The modified layer includes at least two carbon nanotubes layers and at least one cerium oxide/carbon/reduced graphene oxide (CeO(2-x)/C/rGO layer). The carbon nanotubes layer and CeO(2-x)/C/rGO layer are alternately laid on one side surface of the diaphragm substrate and the carbon nanotubes layer is in contact with the diaphragm substrate. The cerium oxide in the CeO(2-x)/C/rGO layer exists in a non-stoichiometric state, where x = 0.1-0.3. USE - Used as composite modified diaphragm for lithium-sulfur battery. ADVANTAGE - The modified diaphragm can inhibit the shuttle effect of lithium-sulfur battery, improves the capacity, rate performance and cycle life of the battery, and has a simple manufacturing method and low cost, and is suitable for large-scale production. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing composite modified separator for lithium-sulfur battery.