• 专利标题:   Preparation of superlattice-type rare-earth-magnesium-nickel-based hydrogen storage alloy involves smelting rare-earth-magnesium-nickel-based alloy, heat-treating in argon atmosphere, milling resulting alloy, and adding graphene.
  • 专利号:   CN104404280-A
  • 发明人:   HE D, HUANG Z, YAN P, YANG Y, WANG D, ZHANG C, WU X, HE K
  • 专利权人:   SHANGHAI NAT ENG RES CENT NANOTECHNOLOGY
  • 国际专利分类:   C22C001/02, C22C001/10, C22C019/03, C22F001/10
  • 专利详细信息:   CN104404280-A 11 Mar 2015 C22C-001/02 201534 Pages: 6 Chinese
  • 申请详细信息:   CN104404280-A CN10707794 01 Dec 2014
  • 优先权号:   CN10707794

▎ 摘  要

NOVELTY - Rare-earth-magnesium-nickel-based alloy is designed. The designed alloy is placed in copper crucible and smelted in high-frequency furnace, the resulting alloy is heat-treated at 800-1000 degrees C for 4-24 hours under degree of vacuum of 1x 102 Pa in argon atmosphere to obtain A2B7 main phase alloy. The resulting alloy is subjected to mechanical milling in inert gas, and graphene is added to obtain superlattice-type rare-earth-magnesium-nickel-based hydrogen storage alloy. USE - Preparation of superlattice-type rare-earth-magnesium-nickel-based hydrogen storage alloy (claimed). ADVANTAGE - The method provides superlattice-type rare-earth-magnesium-nickel-based hydrogen storage alloy having high electrochemical capacity, excellent activation property, and durability. DETAILED DESCRIPTION - Rare-earth-magnesium-nickel-based alloy of formula: (RExMgy)(NikCoaAlbMnc)n is designed, where x is 0.6-0.7, n is 3-4, k+a+b+c is 1, a is 0.1-0.2, b is 0.01-0.1, c is 0-0.1, z is 8 or less, x+y is 1, k+a+b+c is 1, and RE is rare-earth element. The designed alloy is placed in copper crucible and smelted in high-frequency furnace, the resulting alloy is heat-treated at 800-1000 degrees C for 4-24 hours under degree of vacuum of 1x 102 Pa in argon atmosphere to obtain A2B7 main phase alloy. The resulting alloy is subjected to mechanical milling in inert gas, and graphene is added to obtain superlattice-type rare-earth-magnesium-nickel-based hydrogen storage alloy.