• 专利标题:   Preparation of environmentally-friendly flame retardant rubber composite product involves mixing e.g. rubber, curing agent, liquid paraffin, carbon black and tea saponin-based trine intumescent flame retardant-functionalized graphene.
  • 专利号:   CN104877174-A, CN104877174-B
  • 发明人:   WANG N, XU G, ZHANG J
  • 专利权人:   UNIV SHENYANG CHEM TECHNOLOGY
  • 国际专利分类:   C08K013/06, C08K003/04, C08K005/3492, C08K005/521, C08K009/04, C08L007/00
  • 专利详细信息:   CN104877174-A 02 Sep 2015 C08K-009/04 201620 Pages: 6 Chinese
  • 申请详细信息:   CN104877174-A CN10241090 13 May 2015
  • 优先权号:   CN10241090

▎ 摘  要

NOVELTY - Preparation of environmentally-friendly flame retardant rubber composite product involves mixing 100 parts mass rubber, 1.2-1.5 part mass curing agent, 0.8-1 part mass N-cyclohexyl-2-benzothiazole sulfenamide accelerator, 0.2-0.4 part mass tetramethylthiuram disulfide accelerator, 3.5-4.5 parts weight stearic acid, 4.5-5 parts weight zinc oxide, 1-2 parts mass antioxidant 4010, 1-3 parts mass liquid paraffin, 30-40 parts weight carbon black and 2-8 parts mass tea saponin-based trine intumescent flame retardant-functionalized graphene. USE - Preparation of environmentally-friendly flame retardant rubber composite product (claimed). ADVANTAGE - The method enables preparation of environmentally-friendly flame retardant rubber composite product with excellent surface transfer ability, compatibility and carbon bed stability. DETAILED DESCRIPTION - Preparation of environmentally-friendly flame retardant rubber composite product involves mixing 100 parts mass rubber, 1.2-1.5 part mass curing agent, 0.8-1 part mass N-cyclohexyl-2-benzothiazole sulfenamide accelerator, 0.2-0.4 part mass tetramethylthiuram disulfide accelerator, 3.5-4.5 parts weight stearic acid, 4.5-5 parts weight zinc oxide, 1-2 parts mass antioxidant 4010, 1-3 parts mass liquid paraffin, 30-40 parts weight carbon black and 2-8 parts mass tea saponin-based trine intumescent flame retardant-functionalized graphene. The tea saponin-based trine intumescent flame retardant-functionalized graphene is prepared by adding tea saponin and phosphoric acid to a reactor, stirring at 50-60 degrees C for 4-6 hours to reflux, vacuum-filtering reaction mixture at 50-60 degrees C, removing water from the reactor, adding melamine and absolute ethanol to resultant product, stirring at room temperature for 3 hours, obtaining tea saponin-based trine intumescent flame retardant, ultrasonically dispersing graphene in 50-10 ml distilled water, adding 10 mmol/5 mmol 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide/N-hydroxysuccinimide solution, stirring at room temperature for 0.5 hour, adding tea saponin-based trine intumescent flame retardant, and stirring at room temperature for 4-6 hours.