• 专利标题:   Preparation of tungsten trioxide/polyaniline/graphene composite material by dissolving phosphotungstic acid in ethanol, dispersing in hydrochloric acid, adding e.g. aniline and ammonium sulfate, dispersing in graphene oxide and drying.
  • 专利号:   CN106947250-A, CN106947250-B
  • 发明人:   KONG Y, WANG B
  • 专利权人:   UNIV CHANGZHOU, UNIV CHANGZHOU
  • 国际专利分类:   C08G073/02, C08K003/04, C08K003/22, C08L079/02
  • 专利详细信息:   CN106947250-A 14 Jul 2017 C08L-079/02 201771 Pages: 4 Chinese
  • 申请详细信息:   CN106947250-A CN10280689 26 Apr 2017
  • 优先权号:   CN10280689

▎ 摘  要

NOVELTY - Preparation of tungsten trioxide/polyaniline/graphene composite material involves dissolving phosphotungstic acid ethanol, and drying to get tungsten trioxide; ultrasonically dispersing tungsten trioxide in hydrochloric acid solution, adding aniline monomer, adding hydrochloric acid solution and ammonium sulfate, shaking, , centrifuging, washing and freeze-drying to get tungsten trioxide/polyaniline; and dispersing tungsten trioxide/polyaniline in graphene oxide, adding hydrochloric acid, adding zinc powder, sonicating, adding hydrochloric acid, centrifuging, washing, and freeze-drying. USE - Method for preparing tungsten trioxide/polyaniline/graphene composite material (claimed). DETAILED DESCRIPTION - Preparation of tungsten trioxide/polyaniline/graphene composite material comprises preparing tungsten trioxide by weighing phosphotungstic acid, dissolving in ethanol, and drying completely at room temperature for 4 hours; preparing tungsten trioxide/polyaniline by ultrasonically dispersing 0.2 g tungsten trioxide in 10 mL to 1 mol/L hydrochloric acid solution, adding aniline monomer, adding 10 mL 1 mol/L hydrochloric acid solution and ammonium sulfate, quickly shaking at room temperature for 30 seconds, standing for 4 hours, centrifuging, washing, freezing and drying; and dispersing 0.2 g tungsten trioxide/polyaniline in 10 mL 1 mg/mL graphene oxide, adding 0.9 mL concentrated hydrochloric acid, adding zinc powder, sonicating for 30 minutes, adding 1 mL concentrated hydrochloric acid to remove excess zinc powder, centrifuging, washing, freezing and drying.