• 专利标题:   Lithium-ion secondary battery for use in portable information terminals such as mobile phone, smartphone, laptop computer, portable music player, and digital camera, has positive electrode comprising positive electrode active material, where positive electrode active material comprises first region.
  • 专利号:   US2022199984-A1
  • 发明人:   TAKAHASHI M, OCHIAI T, KAWAKAMI T, MOMMA Y
  • 专利权人:   SEMICONDUCTOR ENERGY LAB
  • 国际专利分类:   C01G051/00, H01M010/0525, H01M004/36, H01M004/525, H01M004/62
  • 专利详细信息:   US2022199984-A1 23 Jun 2022 H01M-004/36 202261 English
  • 申请详细信息:   US2022199984-A1 US690057 09 Mar 2022
  • 优先权号:   JP225046

▎ 摘  要

NOVELTY - Lithium-ion secondary battery has positive electrode comprising a positive electrode active material. The positive electrode active material comprises a first region, a second region, a third region, and a fourth region. The first region (101) comprises a composite oxide containing lithium and a first transition metal. The second region (102) comprises lithium, aluminum, oxygen, and a second transition metal. The third region (103) comprises magnesium and oxygen. The fourth region (104) is a covering film which suppresses excessive reaction with electrolytic solution. The first region and the second region each comprises a layered rock-salt crystal structure. The third region comprises a rock-salt crystal structure. The first transition metal is cobalt, manganese, and nickel. The positive electrode active material comprises a region where a portion of the third region overlaps with a portion of the second region. USE - Lithium-ion secondary battery for use in portable information terminals such as mobile phone, smartphone, laptop computer, portable music player, and digital camera ADVANTAGE - The lithium-ion secondary battery has high output and high capacity, excellent charge and discharge characteristic, highly safe or highly reliable secondary battery, improves cycle performance, safe operation under a variety of environment, and longer-term reliability. DETAILED DESCRIPTION - Lithium-ion secondary battery has positive electrode comprising a positive electrode active material. The positive electrode active material comprises a first region, a second region, a third region, and a fourth region. The first region (101) comprises a composite oxide containing lithium and a first transition metal. The second region (102) comprises lithium, aluminum, oxygen, and a second transition metal. The third region (103) comprises magnesium and oxygen. The fourth region (104) is a covering film which suppresses excessive reaction with electrolytic solution. The first region and the second region each comprises a layered rock-salt crystal structure. The third region comprises a rock-salt crystal structure. The first transition metal is cobalt, manganese, and nickel. The positive electrode active material comprises a region where a portion of the third region overlaps with a portion of the second region. The fourth region is in contact with at least a portion of the third region, the fourth region being on a surface side. The crystal orientation of the layered rock-salt crystal structure in the second region is substantially aligned with a crystal orientation of the rock-salt crystal structure in the third region. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic view of the lithium-ion secondary battery. First region (101) Second region (102) Third region (103) Fourth region (104)