• 专利标题:   New nitrogen-15 and nitrogen-14 interspersed uniform nitrogen-doped graphene useful in preparing graphene materials and modified graphene materials.
  • 专利号:   CN113045721-A, CN113045721-B, WO2022174427-A1
  • 发明人:   HUANG M, LUO X, DENG H, JIA Q, PENG S, ZHANG Z, XI S, LIU Y, LIU X, CHI S
  • 专利权人:   BEIJING INST TECHNOLOGY, BEIJING INST TECHNOLOGY
  • 国际专利分类:   B01D053/02, B01J020/26, B01J027/24, B01J031/06, C01B032/194, C08G012/00, C01B032/00
  • 专利详细信息:   CN113045721-A 29 Jun 2021 C08G-012/00 202167 Pages: 27 Chinese
  • 申请详细信息:   CN113045721-A CN10187893 18 Feb 2021
  • 优先权号:   CN10187893

▎ 摘  要

NOVELTY - Nitrogen-15 and nitrogen-14 interspersed uniform nitrogen-doped graphene (I) is new. (I) is prepared by carrying out polycondensation of 15nitrogen and 14nitrogen interspersed hexaaminobenzene hydrochloride compound (II). USE - (I) is useful in preparing graphene materials and modified graphene materials; for characterization or detection of physical and chemical properties of graphene materials and modified graphene materials; for precise chemical structure characterization of uniform nitrogen-doped graphene porous materials; for study of intrinsic physical and chemical properties including optics, acoustics, electrical conductivity and heat conduction; for gas adsorption and separation and their mechanism research; and for study of single-atom catalytic mechanism (claimed). ADVANTAGE - The preparation method: is high efficient and simple; has strong feasibility and economic efficiency; adopts efficient and gentle polycondensation reaction; adopts high-efficiency diazonium salt formation reaction; and achieves nitrogen-15 selective labeling of hexaaminobenzene hydrochloride at 2,4,6-position. (I): ensures the labeled nitrogen-doped graphene material provides a large number of detectable signals by virtue of the periodic and uniformly distributed nitrogen-15 atoms inside the structure. DETAILED DESCRIPTION - Nitrogen-15 and nitrogen-14 interspersed uniform nitrogen-doped graphene of formula (I) is new. (I) is prepared by carrying out polycondensation of nitrogen-15 and nitrogen-14 interspersed hexaaminobenzene hydrochloride compound of formula (II). An INDEPENDENT CLAIM is also included for preparation of (I).