• 专利标题:   Preparing graphene oxide/glycidyl azide polymer-energetic thermoplastic elastomer composite comprises ultrasonically dispersing graphene oxide and tetrahydrofuran, adding graphene oxide dispersion, stirring, allowing to stand, and drying.
  • 专利号:   CN112028725-A
  • 发明人:   LU T, WANG Y, WANG W, LIU W, LU X, CHEN B, LIU Y
  • 专利权人:   XI AN MODERN CHEM RES INST
  • 国际专利分类:   C06B045/10
  • 专利详细信息:   CN112028725-A 04 Dec 2020 C06B-045/10 202004 Pages: 12 Chinese
  • 申请详细信息:   CN112028725-A CN10886215 28 Aug 2020
  • 优先权号:   CN10886215

▎ 摘  要

NOVELTY - Preparing graphene oxide/glycidyl azide polymer-energetic thermoplastic elastomer composite comprises (a) adding graphene oxide to tetrahydrofuran, and ultrasonically dispersing to obtain graphene oxide dispersion, (b) adding glycidyl azide polymer-energetic thermoplastic elastomer to tetrahydrofuran, stirring, dissolving glycidyl azide polymer-energetic thermoplastic elastomer completely to obtain mixed solution of glycidyl azide polymer-energetic thermoplastic elastomer and tetrahydrofuran, and (c) adding graphene oxide dispersion into glycidyl azide polymer-energetic thermoplastic elastomer and tetrahydrofuran mixed solution, stirring the system uniformly, allowing to stand, and drying to obtain graphene oxide/polyglycidyl azide-based energetic thermoplastic elastomer composite. USE - The method is useful for preparing graphene oxide/glycidyl azide polymer-energetic thermoplastic elastomer composite. ADVANTAGE - The method: can improve the thermal stability of the original glycidyl azide polymer-energetic thermoplastic elastomer; can delay thermal decomposition temperature by 1-4.1 degrees C; can reduce the glass transition temperature of the original glycidyl azide polymer-energetic thermoplastic elastomer; can reduce the temperature range of 1.3-3.5 degrees C; and is easy and economical. DETAILED DESCRIPTION - Preparing graphene oxide/glycidyl azide polymer-energetic thermoplastic elastomer composite comprises (a) adding graphene oxide to tetrahydrofuran, and ultrasonically dispersing at 20-35 degrees C for 1-2 hours, where the dosage ratio of graphene oxide and tetrahydrofuran is 10-60 mg: 20-150 g to obtain graphene oxide dispersion, (b) adding glycidyl azide polymer-energetic thermoplastic elastomer to tetrahydrofuran, stirring at 20-35 degrees C for 1-2 hours, dissolving glycidyl azide polymer-energetic thermoplastic elastomer completely to obtain mixed solution of glycidyl azide polymer-energetic thermoplastic elastomer and tetrahydrofuran, where the dosage ratio of glycidyl azide polymer-energetic thermoplastic elastomer to tetrahydrofuran is 4-6 g: 100-200g, and (c) adding graphene oxide dispersion into glycidyl azide polymer-energetic thermoplastic elastomer and tetrahydrofuran mixed solution, stirring the system at 20-40 degrees C for 0.5-1 hour uniformly, allowing to stand at room temperature for 1-2 weeks, and drying at 30-40 degrees C for 2-4 hours to obtain graphene oxide/polyglycidyl azide-based energetic thermoplastic elastomer composite.