▎ 摘 要
NOVELTY - A copper/graphene junction (20) comprises a structure in which a copper component (21) made of copper or a copper alloy and a graphene-containing carbonaceous component (25) containing a graphene aggregate are joined, an active metal carbide layer (41) containing carbides of active metals chosen from titanium, zirconium, niobium, and hafnium between the copper component and the graphene-containing carbonaceous component on the graphene-containing carbonaceous component side, and a magnesium solid solution layer (42) in which magnesium is solid-solved in the matrix phase of copper is formed between the active metal carbide layer and the copper component. USE - Copper/graphene junction used for copper/graphene junction structure (all claimed) for engine compartment, insulation circuit board, and thermoelectric module. ADVANTAGE - The copper/graphene junction has excellent cycle reliability, and suppressed peeling load even under a cold cycle load. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) manufacture of the junction, which involves forming an active metal carbide layer and magnesium solid solution layer, laminating the copper component and the graphene-containing carbonaceous component through active metal carbide layer and magnesium solid solution layer, and the copper component and the graphene-containing carbonaceous component through active metal carbide layer and magnesium solid solution layer by heat treatment in a vacuum atmosphere while being pressurized in the stacking direction, where the content of active metal is 0.4-47.0 mu mol/cm2, and the content of magnesium is 14-180 mu mol/cm2; and (2) a copper/graphene bonded structure. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic view of a bonding interface between a copper component of a copper/graphene junction and a graphene-containing carbonaceous structure. Copper or graphene junction (20) Copper component (21) Graphene-containing carbonaceous structure (25) Bonded interface (40) Active-metal carbide layer (41) Magnesium solid solution layer (42)