▎ 摘 要
NOVELTY - Preparing metal organic frame materials by high pressure homogenization comprises using common organic ligands, inorganic metals or metal clusters as raw materials under room temperature and pressure conditions, where the synthesized metal organic frame (MOFs) comprises but are not limited to isoreticular-MOF (IRMOF), zeolitic imidazolate frameworks (ZIF), circularly polarized luminescence (CPL), MIL, polychlorinated naphthalene (PCN), and UiO series materials, the solvent comprises water or common organic solvents, which include but are not limited to, N,N-dimethylformamide, dioxane, ethanol, acetonitrile, and tetrahydrofuran, and catalysts comprises but are not limited to acetic acid and nitric acid, all commonly used catalysts that can synthesize MOF, which are homogenized by a high-pressure homogenizer for a certain period of time to obtain metal organic framework materials, and the reaction comprises using or not using a templating agent, e.g. use of a templating agent. USE - The method is useful for preparing metal organic frame materials by high pressure homogenization. ADVANTAGE - The method: has continuous reaction, simple operation, low cost, high yield, and short reaction time; is environmentally-friendly; saves energy; is easy to mold powdered MOF; and has the potential for large-scale production, which will greatly promote the industrial production process of MOFs materials. DETAILED DESCRIPTION - Preparing metal organic frame materials by high pressure homogenization comprises using common organic ligands, inorganic metals or metal clusters as raw materials under room temperature and pressure conditions, where the synthesized metal organic frame (MOFs) comprises but are not limited to isoreticular-MOF (IRMOF), zeolitic imidazolate frameworks (ZIF), circularly polarized luminescence (CPL), MIL, polychlorinated naphthalene (PCN), and UiO series materials, the solvent comprises water or common organic solvents, which include but are not limited to, N,N-dimethylformamide, dioxane, ethanol, acetonitrile, and tetrahydrofuran, and catalysts comprises but are not limited to acetic acid and nitric acid, all commonly used catalysts that can synthesize MOF, which are homogenized by a high-pressure homogenizer for a certain period of time to obtain metal organic framework materials, the reaction comprises using or not using a templating agent, e.g. use of a templating agent, where the templating agents used are commonly used aromatic compounds and hydrocarbon substances, the commonly used aromatic compounds and hydrocarbon substances comprise but are not limited to, o-dichlorobenzene, mesitylene, 1,2,4-trichlorobenzene or dioxane, the load or compound used in the reactant comprises but is not limited to a substrate that does not affect the production of MOF, and the substrates that do not affect the production of MOF comprise but are not limited to cellulose, cellulose nanofibrils, cellulose nanocrystals, bacterial nanocellulose, chitosan, and graphene.