• 专利标题:   Preparing new-type mixed substrate gas separation membrane containing amino polyaryletherketone/graphene oxide composite material, comprises e.g. polymerizing bisphenol monomer, mixing with graphene oxide dispersion and paving into membrane.
  • 专利号:   CN113307999-A
  • 发明人:   WANG Z, YANG C, YU J
  • 专利权人:   UNIV CHANGCHUN TECHNOLOGY
  • 国际专利分类:   C08J005/18, C08L071/10, C08K003/04, B01D053/22, B01D067/00, B01D069/12, B01D071/02, B01D071/72
  • 专利详细信息:   CN113307999-A 27 Aug 2021 C08J-005/18 202179 Pages: 9 Chinese
  • 申请详细信息:   CN113307999-A CN10581647 27 May 2021
  • 优先权号:   CN10581647

▎ 摘  要

NOVELTY - Preparing new-type mixed substrate gas separation membrane containing amino polyaryletherketone (Am-PAEK)/graphene oxide composite material, comprises (a) adopting diazonium salt reaction and reductive amination reaction to prepare bisphenol monomer (4-(2,5-diphenol)aniline) containing amino group, (b) adding the bisphenol monomer and difluoro diphenyl ketone into a reaction container by direct polycondensation method to process polymerization and obtain amino polyaryletherketone (Am-PAEK), (c) dissolving the amino polyaryletherketone polymer to obtain a polymer solution, (d) adding a graphene oxide (GO) into deionized water, stirring for 12 hours, then ultrasonically processing for 72 hours at low temperature of 35 degrees C to obtain uniform graphene oxide dispersion liquid, (e) mixing the graphene oxide dispersion and the polymer solution obtained in the step (c) and uniformly stirring, processing ultrasonic treatment, paving into a membrane, and soaking the paved membrane in methanol. USE - The method is useful for preparing new-type mixed substrate gas separation membrane containing amino polyaryletherketone (Am-PAEK)/graphene oxide composite material. ADVANTAGE - The membrane has good gas permeability and separation performance, strong mechanical strength and anti-physical aging performance.