• 专利标题:   Preparing titanium dioxide nanotube-graphene-sulfur composite material comprises e.g. preparing graphene oxide by the Hummers method, dissolving graphene oxide, titanyl sulfate in water and then carrying out hydrothermal reaction.
  • 专利号:   CN108767203-A
  • 发明人:   SUN W, SHI L, LI W, HE W, ZHOU C, LIU X, ZHANG N, CHEN F
  • 专利权人:   ZHEJIANG TIANNENG ENERGY TECHNOLOGY CO
  • 国际专利分类:   H01M004/36, H01M004/38, H01M004/62, H01M010/0525, B82Y030/00, B82Y040/00
  • 专利详细信息:   CN108767203-A 06 Nov 2018 H01M-004/36 201883 Pages: 9 Chinese
  • 申请详细信息:   CN108767203-A CN10261498 28 Mar 2018
  • 优先权号:   CN10261498

▎ 摘  要

NOVELTY - Preparing titanium dioxide nanotube-graphene-sulfur composite material comprises (i) preparing graphene oxide by the Hummers method, (ii) dissolving graphene oxide, titanyl sulfate in water in a mass ratio of 0.2-3:1 and carrying out hydrothermal reaction at 100-200 degrees C for 6-30 hours to obtain crude product, (iii) carbonizing crude product at 400-1000 degrees C under protective gas atmosphere, allowing to stand for 0.5-12 hours, cooling and grinding to obtain titanium dioxide nanotube-graphene composite, and (iv) dispersing titanium dioxide nanotube-graphene composite material and elemental sulfur in a solvent, pressing it into a round cake, sealing and then incubating at 80-200 degrees C for 2-24 hours to obtain final product. USE - The composite material is useful for preparing lithium sulfur battery anode material. ADVANTAGE - The composite material: has excellent cycling stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for titanium dioxide nanotube-graphene-sulfur composite material obtained by above method.