• 专利标题:   Catalyst used for polymerizing for producing olefin, comprises carbon material having preset molar ratio of oxygen with respect to carbon and specific surface area, at least one component containing organoaluminum oxy compound, and transition metal compound.
  • 专利号:   JP2022107508-A
  • 发明人:   HARADA Y, TERAO H
  • 专利权人:   MITSUI CHEM INC
  • 国际专利分类:   C08F010/00, C08F004/64
  • 专利详细信息:   JP2022107508-A 21 Jul 2022 C08F-004/64 202264 Pages: 32 Japanese
  • 申请详细信息:   JP2022107508-A JP186317 16 Nov 2021
  • 优先权号:   JP002295

▎ 摘  要

NOVELTY - A catalyst comprises a carbon material (A), at least one component (B), and (C) transition metal compound (I). The component (B) is chosen from (B-1) an organoaluminum oxy compound and (B-II) a compound that reacts with the transition metal compound (C) to form an ion pair. The component (A) has a molar ratio of oxygen with respect to carbon of 0.018-0.400 in X-ray photoelectron spectroscopy and a specific surface area of 100-5000 m/g by BET multipoint method. USE - Catalyst used for polymerizing for preparing olefin polymer (claimed). Uses include but are not limited to ethylene homopolymer, propylene homopolymer, 4-methyl-1-pentene homopolymer, ethylene/propylene copolymer, ethylene/1-butene copolymer, ethylene/1-hexene copolymer, ethylene/1-octene copolymer, 4-methyl-1-pentene copolymer, propylene/4-methyl-1-pentene copolymer, and 4-methyl-1-pentene/1-decene copolymer. ADVANTAGE - The catalyst has high polymerization activity, and improved the dispersibility of the carbon material in polyolefin. DETAILED DESCRIPTION - A catalyst comprises a carbon material (A), at least one component (B), and (C) transition metal compound of formula: LmMXn (I). The component (B) is chosen from (B-1) an organoaluminumoxy compound and (B-II) a compound that reacts with the transition metal compound (C) to form an ion pair. The component (A) has a molar ratio of oxygen with respect to carbon of 0.018-0.400 in X-ray photoelectron spectroscopy and a specific surface area of 100-5000 m/g by BET multipoint method. M = group 3-11 atoms, or lanthanide atom; L = eta -bonded cyclic anionic ligand, sigma -bonded anionic ligands, or pi -bonded neutral ligands; m = 0 or more; n = 1-6;and X = H, halo, hydrocarbyl, halo-containing group, silicon-containing group, oxygen-containing group, sulfur-containing group, nitrogen-containing group, phosphorus-containing group, or diene derivative group. (i) When n is 2 or more, X can be combine with each other to form a ring. An INDEPENDENT CLAIM is included for production of olefin polymer, which involves (s1) polymerizing an olefin in the presence of the catalyst.