▎ 摘　　要

NOVELTY - Root puncture-resistant mildew-resistant waterproof coiled material includes a copper foil layer whose a upper and lower surfaces are provided with asphalt coating, where the asphalt coating is made of modified asphalt, and the upper and lower surfaces of the asphalt coating are attached with isolation film. The modified asphalt comprises 80-95 pts. wt. asphalt, 8-10 pts. wt. naphthenic oil, 6-8 pts. wt. styrene-butadiene-styrene block copolymer, 5-8 pts. wt. powdered styrene-butadiene rubber, 4-6 pts. wt. modified graphene oxide, 5-7 pts. wt. modified talc powder and 3-5 pts. wt. antioxidant. USE - Root puncture-resistant mildew-resistant waterproof coiled material for a planting roof system of a green plant as a main covering, nutrition soil layer needed by plant survival, water storage layer and plant root blocking layer. ADVANTAGE - The coiled material utilizes copper foil as the middle layer, so that the copper can prevent the growth of bacteria on its surface, improve the service life of the waterproof coiled material, and resist the damage of plant roots, and with the modified graphene oxide in the modified asphalt to improve the effect of root puncture resistance. The raw material for the preparation of the whole asphalt coating, styrene butadiene styrene block copolymer is added to the raw material to form a continuous and crossed network structure between the polymers of the raw material, and introduced modified graphene oxide to further form a "protective layer" of multi-layer structure, hinders the immersion of corrosive media, and the mutual cooperation of the materials in the asphalt coating is more conducive to improving the chemical corrosion resistance of the material. DETAILED DESCRIPTION - Root puncture-resistant mildew-resistant waterproof coiled material includes a copper foil layer whose upper and lower surfaces are provided with asphalt coating, where the asphalt coating is made of modified asphalt, and the upper and lower surfaces of the asphalt coating are attached with isolation film. The modified asphalt comprises 80-95 pts. wt. asphalt, 8-10 pts. wt. naphthenic oil, 6-8 pts. wt. styrene-butadiene-styrene block copolymer, 5-8 pts. wt. powdered styrene-butadiene rubber, 4-6 pts. wt. modified graphene oxide, 5-7 pts. wt. modified talc powder and 3-5 pts. wt. antioxidant. The modified graphene oxide is prepared by (a) mixing ethyl 2-(4-chloro-2-methylphenoxy)propionate, 1,4-butanediol and a catalyst, heating under reflux at 120℃ for 6 hours, after reacting, cooling the temperature to room temperature, then extracting the obtained reaction solution with dichloromethane and deionized water, drying the obtained organic phase with anhydrous sodium sulfate, and concentrating under reduced pressure after drying to obtain the root inhibitor component, and (b) under the condition of nitrogen protection, adding the root inhibitor component to the dispersion liquid containing cyanate-modified graphene, setting the temperature at 80℃, stirring the reaction for 20 hours, after reacting, cooling to room temperature, precipitating the obtained reaction solution with acetone, and drying the obtained precipitate to constant weight at 80℃ under vacuum conditions to obtain modified graphene oxide. An INDEPENDENT CLAIM is included for a preparation method of the waterproof coiled material, comprising (a1) taking the raw material of modified asphalt according to parts by weight, putting the weighed raw material into the internal mixer and mixing evenly to obtain the mixture, and (b1) passing the mixture through the extruder and then extruded through a mold, rolling the processed material and copper foil layer, forming by a rolling machine, after cooling, forming an asphalt coating, and finally attaching the isolation film to the surface of the asphalt coating to obtain a root puncture-resistant mildew-resistant waterproof membrane.