• 专利标题:   Method for preparing grapheme-supported palladium catalyst that is utilized in formic acid fuel cell, involves stirring graphene and phosphomolybdic acid, followed by carrying out ultrasonic treatment, stirring, filtering and drying.
  • 专利号:   CN106129423-A, CN106129423-B
  • 发明人:   YUAN W, FAN X, LI C
  • 专利权人:   UNIV SOUTHWEST
  • 国际专利分类:   H01M004/92, H01M008/1009
  • 专利详细信息:   CN106129423-A 16 Nov 2016 H01M-004/92 201682 Pages: 9 Chinese
  • 申请详细信息:   CN106129423-A CN10479588 27 Jun 2016
  • 优先权号:   CN10479588

▎ 摘  要

NOVELTY - A graphene-supported palladium catalyst preparing method involves stirring graphene and phosphomolybdic acid, and filtering to obtain solid. The solid is washed with water and dried to obtain phosphomolybdic acid modified-graphene, followed by mixing palladium chloride with hydrochloric acid, diluting with secondary water to obtain tetrachloropalladinic acid solution, adjusting pH, adding modified-graphene with tetrachloropalladinic acid solution to carry out ultrasonic treatment, stirring with ascorbic acid, filtering, washing with secondary water and drying to obtain finished product. USE - Method for preparing grapheme-supported palladium catalyst that is utilized in formic acid fuel cell (claimed). ADVANTAGE - The method enables preparing the grapheme-supported palladium catalyst with high dispersibility, better catalytic activity, better stability and wide application range. DETAILED DESCRIPTION - A graphene-supported palladium catalyst preparing method involves ultrasonically stirring 5-50 mg graphene and 10-100 ml of 10 mg/ml phosphomolybdic acid for 1-5 hours, and filtering the stirred mixture to obtain solid. The solid is washed with water and dried in a vacuum drying box at 70-90 degrees C for 6-24 hours to obtain a phosphomolybdic acid modified-graphene, followed by mixing 100-300 mg palladium chloride with 100-300 ml of 1M hydrochloric acid to obtain tetrachloropalladinic acid stock solution, diluting 1-2 ml stock solution with 10-11 ml secondary water to obtain tetrachloropalladinic acid solution, adjusting pH of tetrachloropalladinic acid solution to 3-7 with alkali and adding phosphomolybdic acid modified-graphene with tetrachloropalladinic acid solution to carry out ultrasonic treatment for 5-20 minutes. The resultant solution is stirred with 1-5 ml of 13-15 mg/ml ascorbic acid for 8-24 hours, followed by filtering the resultant solution to obtain a solid product, washing the solid product with secondary water and drying in a vacuum drying oven at 70-90 degrees C for 8-24 hours to obtain the finished product. An INDEPENDENT CLAIM is also included for a grapheme-supported palladium catalyst.