• 专利标题:   Preparation of nitrogen-doped graphene composite cathode for degrading organic pollutants, involves adding ethanol to nitrogen-doped graphene-carbon black mixture, coating on graphite electrode and calcining.
  • 专利号:   CN107739074-A
  • 发明人:   ZHOU M, YANG W, LIANG L
  • 专利权人:   UNIV NANKAI
  • 国际专利分类:   C02F001/461, C02F001/72, C02F101/30
  • 专利详细信息:   CN107739074-A 27 Feb 2018 C02F-001/461 201825 Pages: 6 Chinese
  • 申请详细信息:   CN107739074-A CN10815000 08 Sep 2017
  • 优先权号:   CN10815000

▎ 摘  要

NOVELTY - Preparation of highly catalytically active nitrogen-doped graphene composite cathode involves mixing graphene and ammonium nitrate, reacting at 300-400 degrees C for 0.5-2 hours, cooling, washing, vacuum-filtering, drying at 55 degrees C, mixing resultant nitrogen-doped graphene with carbon black in the mass ratio of 1:1-1:5, adding 0.3-0.6 ml polytetrafluoroethylene, 1-2 ml ethanol and 1-2 ml deionized water, mixing, uniformly coating on both sides of graphite felt electrode pretreated with acetone solution, and calcining at 360 degrees C for 30-40 minutes. USE - Preparation of highly catalytically active nitrogen-doped graphene composite cathode used for degrading organic pollutants (claimed). ADVANTAGE - The method efficiently provides highly catalytically active nitrogen-doped graphene composite cathode with reduced consumption of energy without affecting the environment. DETAILED DESCRIPTION - Preparation of highly catalytically active nitrogen-doped graphene composite cathode involves mixing graphene as carbon source prepared by electrochemical stripping and ammonium nitrate as nitrogen source in the mass ratio of 1:1-1:10 under nitrogen atmosphere, reacting at 300-400 degrees C for 0.5-2 hours, cooling, washing, vacuum-filtering, drying at 55 degrees C, mixing resultant nitrogen-doped graphene with carbon black in the mass ratio of 1:1-1:5, adding 0.3-0.6 ml polytetrafluoroethylene, 1-2 ml ethanol and 1-2 ml deionized water, mixing, uniformly coating on both sides of graphite felt electrode pretreated with acetone solution, and calcining at 360 degrees C for 30-40 minutes. An INDEPENDENT CLAIM is included for organic pollutant degradation method, which involves carrying out degradation of organic pollutants using nitrogen-doped graphene composite cathode as cathode, and high oxygen evolution potential electrode such as dimensionally stable anode or metal oxide as anode, under control working voltage of 2.5-5 V and aeration rate of 0.5-1 L/minutes.