• 专利标题:   Preparing microemulsion cutting fluid useful for aluminum alloy processing of aeroengine, comprises e.g. dissolving graphene oxide in deionized water, ultrasonically dispersing, dissolving sulfonamide and nitrate in hydrochloric acid solution, stirring, ball milling and mixing.
  • 专利号:   CN113652292-A
  • 发明人:   CHEN Y, XIE X
  • 专利权人:   SICHUAN OULITAIER NEW MATERIAL CO LTD
  • 国际专利分类:   C10M173/00, C10N030/06
  • 专利详细信息:   CN113652292-A 16 Nov 2021 C10M-173/00 202234 Chinese
  • 申请详细信息:   CN113652292-A CN10934857 13 Aug 2021
  • 优先权号:   CN10934857

▎ 摘  要

NOVELTY - Preparing microemulsion cutting fluid comprises (i) dissolving graphene oxide in deionized water, and ultrasonically dispersing for 2-3 hours to form brown dispersion solution, slowly adding sodium borohydride at 60-80degreesC and stirring for 1-3 hours, (ii) dissolving sulfonamide and nitrate in a hydrochloric acid solution, stirring magnetically for 4-6 hours under ice bath conditions, (iii) adding sulfonated graphene/MoS2 nanocage into a ball mill, ball milling at a speed of 1200-1500 revolutions/minute for 2-3 hours, (iv) taking 25-28 pts. wt. biodegradable base oil, and adding 6-8 pts. wt. OP-10 NP emulsifier and mixing, (v) taking 110-135 pts. wt. deionized water, adding 26-34 pts. wt. sulfonated graphene/MoS2 nanocage, 6-9 pts. wt. glycerin and 3-5 pts. wt. propylene glycol, and stirring, and (vi) mixing the oil-based mixture and water-based mixture, stirring at 720-850 revolutions/minute until the liquid is uniform and transparent. USE - The fluid is useful for aluminum alloy processing of aeroengine. DETAILED DESCRIPTION - Preparing microemulsion cutting fluid comprises (i) dissolving graphene oxide in deionized water, and ultrasonically dispersing for 2-3 hours to form brown dispersion solution, adjusting the pH to 9-10 with carbonate solution, slowly adding sodium borohydride at 60-80degreesC and stirring for 1-3 hours, re-dispersing the partially reduced graphene oxide in deionized water, and the pH value is neutral 7 after centrifuging and washing with deionized water for 3-5 times, (ii) dissolving sulfonamide and nitrate in a hydrochloric acid solution with a mass ratio of 23:9, slowly adding the mixture to the dispersion solution with a pH of 7, and stirring magnetically for 4-6 hours under ice bath conditions, dispersing the product in deionized water again for dispersion, centrifuging and washing with deionized water for 3-5 times, adding hydrazine hydrate, and magnetically stirring at 100degreesC for 24-36 hours, centrifuging and washing with deionized water for 3 to 5 times to obtain sulfonated graphene, dispersing the sulfonated graphene in deionized water and ultrasonically processing for 2-3 hours to form a uniform dispersion, adding soluble molybdenum salt and sulfur powder to hydrazine hydrate and N,N-dimethylformamide to form a brown mixed liquid, the volume ratio of hydrazine hydrate and N,N-dimethylformamide is 1:1 under the condition of (10000-15000 revs/min), adding the brown mixed liquid dropwise to the sulfonated graphene dispersion, and adding hydrogen peroxide at the same time, centrifuging the obtained product, washing with deionized water for 3-5 times, and freeze-drying 12-24 hours finally formed sulfonated graphene/MoS2 nanocage, (iii) adding the sulfonated graphene/MoS2 nanocage into a ball mill, ball milling at a speed of 1200-1500 revolutions/minute for 2-3 hours, and placing sulfonated graphene/MoS2 nanocage in ethylene glycol 4-6 times its weight, adding 2-3 pts. wt. dimethyl sulfate and 1-2 pts. wt. sodium dodecyl sulfonate, stirring evenly, ultrasonically processing for 20-25 minutes, the ultrasonic frequency is 240-360 kHz, (iv) taking 25-28 pts. wt. biodegradable base oil, and adding 6-8 pts. wt. OP-10 NP emulsifier and mixing, adding 3-4 pts. wt. triethanolamine, 2-4 pts. wt. polyethylene wax, 2-3 pts. wt. complex surfactant, 1-3 pts. wt. barium petroleum sulfonate rust inhibitor and 1-2 pts. wt. polyether defoamer, stirring, (v) taking 110-135 pts. wt. deionized water, and adding 26-34 pts. wt. sulfonated graphene/MoS2 nanocage, 6-9 pts. wt. glycerin and 3-5 pts. wt. propylene glycol, and stirring, and (vi) mixing the oil-based mixture and water-based mixture, stirring at 720-850 revolutions/minute until the liquid is uniform and transparent.