• 专利标题:   Azo derivative-grafted graphene quantum dot composite material used in e.g. sensor for detection of heavy metal ion, is obtained by connecting specific groups of p-aminobenzene sulfonic azobenzene with acid chlorinated graphene quantum dot.
  • 专利号:   CN107488135-A
  • 发明人:   WU B, YANG L, WANG X
  • 专利权人:   UNIV PUTIAN
  • 国际专利分类:   C07C303/22, C07C309/45, C09K011/06, C09K011/65, C09K009/02, G01N021/64
  • 专利详细信息:   CN107488135-A 19 Dec 2017 C07C-303/22 201811 Pages: 8 Chinese
  • 申请详细信息:   CN107488135-A CN10595556 20 Jul 2017
  • 优先权号:   CN10595556

▎ 摘  要

NOVELTY - An azo derivative-grafted graphene quantum dot composite material is obtained by connecting hydroxyl group on benzene ring of one side of p-aminobenzene sulfonic azobenzene with acid chloride group on acid chlorinated graphene quantum dot. USE - Azo derivative-grafted graphene quantum dot composite material is used in sensor for detection of heavy metal ion (claimed), biomedical applications, optical and electrical devices, solar cell, electronic devices, optical particulate fuel and composite system. ADVANTAGE - The azo derivative-grafted graphene quantum dot composite material has strong identifying ability of metal ions in molecular fluorescence, and excellent selectivity and stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the composite material, which involves using acid chlorinated graphene quantum dots prepared using graphene quantum dots and mixed solution of acyl chloride and organic solvent, p-aminobenzene sulfonic azobenzene and tetrahydrofuran in a mass ratio of 1:1-3:200-300, and ethanol. The acyl chloride is thionyl chloride, phosphorus trichloride, phosphorus pentachloride or phosphorus oxychloride. The organic solvent is anhydrous N,N-dimethylformamide, tetrahydrofuran, cyclohexane, benzene or toluene.