• 专利标题:   Anode material for sodium-ion battery, comprises sodium nickel-metal oxide containing conductive carbon with preset specific area and particle diameter contains manganese and graphene.
  • 专利号:   CN112864389-A, CN112864389-B, WO2022160534-A1
  • 发明人:   SHI S, QI C, ZHANG L, MA C, WANG Y
  • 专利权人:   SHANDONG YUHUANG NEW ENERGY TECHNOLOGY, SHANDONG YUHUANG NEW ENERGY TECHNOLOGY
  • 国际专利分类:   B82Y030/00, H01M010/054, H01M004/505, H01M004/525, H01M004/62
  • 专利详细信息:   CN112864389-A 28 May 2021 H01M-004/62 202154 Pages: 12 Chinese
  • 申请详细信息:   CN112864389-A CN10106561 26 Jan 2021
  • 优先权号:   CN10106561

▎ 摘  要

NOVELTY - An anode material comprises sodium nickel-metal oxide and 1-10 wt.% conductive carbon and has a specific area of 0.3-1.2 m2/g and D50 particle diameter of 5-30 nm. The conductive carbon comprises at least one of graphene, carbon nanotube, conductive carbon black, and acetylene black. USE - Anode material used for sodium-ion battery (claimed). ADVANTAGE - The anode material is nano-sized, has high dispersibility, and large specific surface area. The battery comprising the anode material has improved cycle performance and performance rate, charge and discharge capacity, specific capacity, cycle stability, and service life. DETAILED DESCRIPTION - An anode material comprises sodium nickel-metal oxide and 1-10 wt.% conductive carbon and has a specific area of 0.3-1.2 m2/g and D50 particle diameter of 5-30 nm. The conductive carbon comprises at least one of graphene, carbon nanotube, conductive carbon black, and acetylene black. The sodium nickel-metal oxide is of formula: NaxNiyM1-yO2, where x is 0.5-1, y is 0.1-0.5 and M is at least one of manganese, iron, zinc, silver, zirconium, vanadium, molybdenum, niobium, copper, chromium, and titanium. An INDEPENDENT CLAIM is included for the preparation of anode material which involves (1) mixing a sodium salt, nickel salt, (M) salt, conductive carbon, and a solvent to form a mixed slurry, (2) atomizing and directly calcining.