• 专利标题:   Modified graphene doped lithium titanate composite cathode material comprises lithium titanate material which is coated or doped with doped graphene.
  • 专利号:   CN105680007-A, CN105680007-B
  • 发明人:   LI Z, LIU L, SONG C
  • 专利权人:   LI Z, LIU L, LI Z, LIU L
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/485, H01M004/587, H01M004/62
  • 专利详细信息:   CN105680007-A 15 Jun 2016 H01M-004/36 201655 Pages: 6 Chinese
  • 申请详细信息:   CN105680007-A CN10020596 13 Jan 2016
  • 优先权号:   CN10020596

▎ 摘  要

NOVELTY - A modified graphene doped lithium titanate composite cathode material comprises lithium titanate material which is coated or doped with doped graphene. The doped graphene is coated or doped at 10-20 wt.%. USE - Modified graphene doped lithium titanate composite cathode material. ADVANTAGE - The composite cathode material has improved conductivity, increased capacity and high-rate charge and discharge characteristics. The production method of the composite cathode material is easy to operate, and suitable for industrial large scale production. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the preparation of modified graphene doped lithium titanate composite cathode material comprising: (A) mixing raw material and doped graphene oxide an grinding, under an inert atmosphere, heating at 600-800 degrees C for 6-8 hours, cooling to obtain doped graphene, where the doping element is present at 8-10 wt.%; (B) preparing lithium titanate precursor according to mol ratio of lithium to titanium at 0.84 and weighed lithium carbonate and titanium dioxide, ball milling in ethanol for 2-4 hours in mixed dispersion medium, drying, heating at 500-600 degrees C for 6-8 hours, and cooling to obtain lithium titanate precursor powder; and (C) ball milling the graphene doped with lithium titanate precursor, where the weight ratio of the doped graphite to alkenyl lithium titanate precursor is 1:4-1:9, heating under an inert atmosphere at 800-1000 degrees C for 8-12 hours, and cooling to obtain doped graphene, where the coating amount of lithium titanate composite material is 1-20%, and the inert atmosphere is argon or helium atmosphere.