• 专利标题:   Preparing inorganic fiber reinforced thermoplastic polyurethane composite material, comprises e.g. adding gamma-aminopropyltriethoxysilane into anhydrous ethanol, reacting acetic acid, adding graphene and carbon fibers, obtaining surface-modified inorganic fibers and post-processing.
  • 专利号:   CN114855300-A
  • 发明人:   XU W, LIU X, LI X, XIA L, ZHANG J, ZHANG C
  • 专利权人:   UNIV WUHAN TEXTILE
  • 国际专利分类:   D01D001/02, D01D005/06, D01F001/10, D01F006/94
  • 专利详细信息:   CN114855300-A 05 Aug 2022 D01F-006/94 202287 Chinese
  • 申请详细信息:   CN114855300-A CN10465284 29 Apr 2022
  • 优先权号:   CN10465284

▎ 摘  要

NOVELTY - Preparing inorganic fiber reinforced thermoplastic polyurethane composite material, comprises (i) adding coupling agent to anhydrous ethanol, mixing uniformly, adding acetic acid to hydrolyze coupling agent, adding nanoparticles and inorganic fibers, reacting for 0.5-6 hours, washing and drying to obtain surface-modified inorganic fibers, (ii) mixing toluene and N,N dimethylformamide to obtain binary solvent, adding preset proportion of polyurethane resin particles and the surface-modified inorganic fibers into binary solvent, ultrasonically dispersing, mechanically stirring uniformly and vacuum defoaming to obtain inorganic fiber polyurethane composite spinning solution, and (iii) adding inorganic fiber-polyurethane composite spinning solution to wet spinning machine for spinning at certain spinning speed, spinning thin stream comes out of coagulation bath, drafting treatment, forming complete fiber, using high temperature heat setting and drying to obtain the final product. USE - The method is useful for preparing inorganic fiber reinforced thermoplastic polyurethane composite material. ADVANTAGE - The method enables to prepare inorganic fiber reinforced thermoplastic polyurethane composite material having excellent mechanical properties. DETAILED DESCRIPTION - Preparing inorganic fiber reinforced thermoplastic polyurethane composite material, comprises (i) adding coupling agent to anhydrous ethanol, mixing uniformly, adding acetic acid to hydrolyze coupling agent, adding nanoparticles and inorganic fibers, reacting for 0.5-6 hours, washing and drying to obtain surface-modified inorganic fibers, (ii) mixing toluene and N,N dimethylformamide to obtain binary solvent, adding preset proportion of polyurethane resin particles and the surface-modified inorganic fibers into binary solvent, ultrasonically dispersing for 5-10 minutes at 20-30 ℃, mechanically stirring uniformly and vacuum defoaming to obtain inorganic fiber polyurethane composite spinning solution, and (iii) adding inorganic fiber-polyurethane composite spinning solution to wet spinning machine for spinning at certain spinning speed, spinning thin stream comes out of coagulation bath, drafting treatment, forming complete fiber, using high temperature heat setting and drying to obtain the final product. An INDEPENDENT CLAIM is also included for an inorganic fiber reinforced thermoplastic polyurethane composite material obtained by the above method.