• 专利标题:   COMPOSITE MEMBRANE FOR DRYING NATURAL AND PROCESS GAS MIXTURES BASED ON GRAPHENE OXIDE INTERCALATED WITH HYDROXYLATED FULLERENE DERIVATIVES.
  • 专利号:   RU2730320-C1
  • 发明人:   BROTSMAN V A, CHERNOVA E A, PETUKHOV D I, LUKASHIN A V, ELISEEV A A
  • 专利权人:   UNIV MOSC LOMONOSOV
  • 国际专利分类:   B01D053/28, B01D069/12, B01D071/02, B82Y030/00, C01B032/156, C01B032/198
  • 专利详细信息:   RU2730320-C1 21 Aug 2020 B01D-071/02 202076 Pages: 0 Russian
  • 申请详细信息:   RU2730320-C1 RU145182 30 Dec 2019
  • 优先权号:   RU145182

▎ 摘  要

NOVELTY - Invention relates to nanotechnology and membrane technology. Composite membrane comprises a nanoporous substrate and 20200 nm thick selective layer containing nano-sheets of graphene oxide intercalated with fullerenols C60(OH)n or C70(OH)n, where n=1040, uniformly distributed between graphene oxide nano-sheets. Content of fullerenols in selective layer from 5 to 33 wt%. Size of nano-graphene oxide from 500 to 5,000 nm, C/O ratio in range from 1.2 to 2.1. Substrate is made from nanoporous inorganic or polymer material with pore diameter from 20 to 500 nm, for example, from anodized aluminum oxide, cellulose acetate (AC), or from hollow fiber based on polypropylene (PP), polysulphone (PS), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE). USE - Nanotechnologies. ADVANTAGE - Composite membrane is intended for drying natural and process gas mixtures and has barrier properties with respect to gases such as N2, O2, CH4, C4H10, and good permeability and selectivity with respect to water vapor and such water-soluble gases as CO2, H2S, high time stability and resistance to pressure drops in baromembrane processes. 8 cl, 5 dwg, 1 tbl, 12 ex