• 专利标题:   Highly conductive graphene fiber useful in e.g. preparation of flexible solar cells, comprises fiber of graphene along the axial direction in an ordered array and doping between the graphene layers with e.g. iodine bromide as dopant,.
  • 专利号:   CN105544017-A, CN105544017-B
  • 发明人:   GAO C, LIU Y, XU Z
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   D01D005/06, D01F011/12, D01F009/12
  • 专利详细信息:   CN105544017-A 04 May 2016 D01F-009/12 201643 Pages: 7 English
  • 申请详细信息:   CN105544017-A CN10054970 27 Jan 2016
  • 优先权号:   CN10054970

▎ 摘  要

NOVELTY - Highly conductive graphene fiber comprises the fiber of graphene along the axial direction in an ordered array with the graphene layer spacing of 0.3-0.4 nm and doping between the graphene layers with iodine bromide, iodine chloride, potassium, calcium, ferric chloride, molybdenum chloride, aluminum chloride and/or copper chloride as dopant, where the dopant comprises 10-30% graphene and the fiber orientation of graphene is 80-90%. USE - The highly conductive graphene fiber is useful in the preparation of flexible solar cells, super capacitor and wearable devices, as light conductors, for ultra light wire and cable that can replace metal copper wire and for generation of power transmission. ADVANTAGE - The method: is simple and controllable; improves conductive properties of graphene fiber; and produces graphene fibers having high mechanical properties and electrical conductivity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing highly conductive graphene fiber comprising (a) taking 1 pts. wt. graphene oxide and 10-100 pts. wt. solvent mixture and ultrasonically dispersing, to obtain graphene oxide spinning liquid, (b) extruding graphene oxide spinning liquid at a rate of 1-100 ml/hour, where the pore size of the spinning head is 30-300 mu m, placing in the coagulating bath at 10-50 degrees C for 5-60 seconds and collecting, to obtain continuous graphene oxide fiber, (c) reducing graphene oxide fibers by the reducing agent, washing and drying, to obtain primary graphite fiber, (d) placing primary graphite fiber in a graphite furnace at 1000-3000 degrees C and atmospheric heat treating for 1-4 hours, to obtain high quality graphene fiber and (e) treating the high quality graphene fiber in the steam of dopant for 1-24 hours.