• 专利标题:   Method for producing tin oxide-graphene aerosol used for producing lithium-ion battery cathode, involves adding graphene oxide water liquid to ammonia water, adding tin to mixture, and reacting and freeze-drying.
  • 专利号:   CN103904313-A, CN103904313-B
  • 发明人:   CAI F, HU S, JIANG B, TAN C, YANG G
  • 专利权人:   ENERGY RES INST SHANDONG ACAD SCI
  • 国际专利分类:   H01M004/48, H01M004/62
  • 专利详细信息:   CN103904313-A 02 Jul 2014 H01M-004/48 201460 Pages: 7 Chinese
  • 申请详细信息:   CN103904313-A CN10150954 15 Apr 2014
  • 优先权号:   CN10150954

▎ 摘  要

NOVELTY - A tin oxide-graphene aerosol producing method involves preparing graphene oxide water dispersion liquid. Prepared graphene oxide water dispersion liquid is added to concentrated aqueous ammonia water and stirred. Tin source is added to the mixture and stirred. Polyvinyl pyrrolidone is added to mixture, and dispersed ultrasonically. Obtained mixture is transferred to a hydrothermal reactor for performing hydrothermal reaction, dialyzed with ultrapure water and then freeze dried. Freeze-dried sample is dried and heat-treated. USE - Method for producing tin oxide-graphene aerosol used for producing lithium-ion battery cathode (claimed). ADVANTAGE - The method enables producing tin oxide-graphene aerosol with certain toughness, and eliminating usage of conductive agent and binder, thus reducing cost of lithium ion battery and improves assembling technology of battery. DETAILED DESCRIPTION - A tin oxide-graphene aerosol producing method, involves preparing graphene oxide water dispersion liquid with concentration of 0.5-5 mg/ml by Hummers method. 300mg prepared graphene oxide water dispersion liquid is added to 1-3 ml concentrated aqueous ammonia water and stirred uniformly. 0-1 g tin source is added to the mixture and stirred to dissolve completely. 20-100 mg polyvinylpyrrolidone with average molecular weight of 55000 is added to mixture containing 400 mg tin source, and dispersed ultrasonically for 2 hours. Obtained mixture is transferred to a hydrothermal reactor for performing hydrothermal reaction at 100-300 degrees C for 1-24 hours. Obtained sample is dialyzed with ultrapure water for one day and frozen at -20 degrees C for 4 hours, and then freeze dried at -53 degrees C and 30Pa for 12 hours. Freeze-dried sample is dried at 70 degrees C for 10 hours under vacuum and heat-treated at 550 degrees C for 3 hours under argon gas atmosphere. Tin source is chosen from tin tetrachloride, stannous sulfate, stannous chloride, and their mixtures.