• 专利标题:   New Schiff base lead composite used as combustion catalyst, is prepared by placing graphene oxide ethanol dispersion in three-necked flask, adding N-aminoethyl-gamma-aminopropyltrimethoxysilane ethanol solution, reacting and cooling.
  • 专利号:   CN110330394-A
  • 发明人:   ZHANG M, ZHAO F, LI H, YANG Y, JIANG Z
  • 专利权人:   XI AN MODERN CHEM RES INST
  • 国际专利分类:   C06B023/00, C06D005/00
  • 专利详细信息:   CN110330394-A 15 Oct 2019 C06B-023/00 201986 Pages: 9 Chinese
  • 申请详细信息:   CN110330394-A CN10724290 07 Aug 2019
  • 优先权号:   CN10724290

▎ 摘  要

NOVELTY - A Schiff base lead composite (I), is new. USE - New Schiff base lead composite used as combustion catalyst. ADVANTAGE - The compound (I) has good compatibility with modified double base propellant containing octogen and absorbent. DETAILED DESCRIPTION - A Schiff base lead composite of formula (I), is new. An INDEPENDENT CLAIM is included for preparation of compound (I) which involves placing graphene oxide ethanol dispersion in three-necked flask, adding N-aminoethyl- gamma -aminopropyltrimethoxysilane ethanol solution in drops, reacting under reflux for 2 hours, cooling to room temperature, centrifuging, washing with ethanol to obtain aminated graphene, placing the aminated graphene ethanol dispersion in a three-necked flask, adding salicylaldehyde ethanol solution in drops, reacting under reflux 3 hours, cooling to room temperature, centrifuging, washing with ethanol to obtain graphene-Schiff base complex, mixing graphene-Schiff base complex with lead nitrate aqueous solution, reacting at 50-60 degrees C for 4 hours, cooling to room temperature, centrifuging and washing with ethanol. The mass ratio of N-aminoethyl- gamma -aminopropyltrimethoxysilane to graphene oxide is 10-15:1. The mass ratio of salicylaldehyde to aminated graphene is 5-10:1. The mass ratio of graphene-Schiff base complex to lead nitrate is 0.5-1:1. The volume ratio of ethanol to water is 2-5:1.