▎ 摘　　要

NOVELTY - High toughness graphene modified rubber material comprises e.g. silicon rubber, fluorine rubber, graphene, EVA resin, dibutyl phthalate, glycerol triglyceride, acrylic acid stearate, maleic anhydride grafted, magnesium hydroxide, kaolin, dolomite powder, calcium hexadecylsulfonate, zinc diethyldithiocarbamate, chlorinated polyethylene, isoprene, polyethylene wax, polyethylene terephthalate fiber, dimethyl silicone oil, carbon fiber, polyamide fiber, carboxyethylcellulose, surfactant, initiator, chain extender, crosslinking agent, degreasing agent, catalyst, accelerator and leveling agent. USE - The material is useful for manufacturing tires, rubber tube, tape, and cable product. DETAILED DESCRIPTION - High toughness graphene modified rubber material comprises 79-102 pts. wt. silicon rubber, 50-61 pts. wt. fluorine rubber, 43-63 pts. wt. graphene, 24-34 pts. wt. EVA resin, 16-21 pts. wt. dibutyl phthalate, 13-25 pts. wt. glycerol triglyceride, 12-15 pts. wt. acrylic acid stearate, 16-23 pts. wt. maleic anhydride grafted, 4-6 pts. wt. magnesium hydroxide, 7-10 pts. wt. kaolin, 5-9 pts. wt. dolomite powder, 4-8 pts. wt. calcium hexadecylsulfonate, 5-12 pts. wt. zinc diethyldithiocarbamate, 12-16 pts. wt. chlorinated polyethylene, 12-16 pts. wt. isoprene, 14-23 pts. wt. polyethylene wax, 9-15 pts. wt. polyethylene terephthalate fiber, 8-13 pts. wt. dimethyl silicone oil, 7-12 pts. wt. carbon fiber, 4-6 pts. wt. polyamide fiber, 5-9 pts. wt. carboxyethylcellulose, 0.6-1.2 pts. wt. surfactant, 0.4-0.6 pts. wt. initiator, 0.6-0.8 pts. wt. chain extender, 0.3-0.5 pts. wt. crosslinking agent, 0.3-0.4 pts. wt. degreasing agent, 0.4-0.7 pts. wt. leveling agent, 0.2-0.4 pts. wt. catalyst, 0.2-0.3 pts. wt. accelerator, 0.3-0.5 pts. wt. plasticizer, 0.2-0.4 pts. wt. dispersant, 0.3-0.4 pts. wt. tackifier, 0.7-1.1 pts. wt. curing agent, 0.6-1.2 pts. wt. antibacterial agent, 0.4-0.6 pts. wt. antioxidant, 0.4 pts. wt., heat stabilizer 0.1-0.2 pts. wt., 0.6-1.2 pts. wt. anti-aging agent, 0.4-0.6 pts. wt. ultraviolet absorber, 1.2-1.5 pts. wt. flame retardant and 0.5-0.8 pts. wt. smoke suppressing agent; where the dispersant is a dispersant NC; the tackifier is butyltrimethoxysilane; the curing agent is an epoxy resin curing agent; the antibacterial agent is lithium carbonate; the antioxidant is an antioxidant Agent 1010; the light stabilizer is a light stabilizer 770; the heat stabilizer is a salt of di-salt phthalate; the anti-aging is a BASF UV-234 antioxidant; the ultraviolet absorber is phenyl ortho-hydroxybenzoate; The flame retardant comprises, 48-65 pts. wt. ethylene glycol ether acetate, 20-34 pts. wt. benzene-free epoxy resin, 18-25 pts. wt. fatty alcohol polyoxyethylene ether sulfate, 12-22 pts. wt. tripentaerythritol, 10-16 pts. wt. urea, 7-12 pts. wt. alumina, 9-12 pts. wt. antimony trioxide, 5-9 pts. wt. manganese oxide, 8-12 pts. wt. activated clay, 1.3-1.8 pts. wt. penetrant and 0.8-1.2 pts. wt. synergist; the smoke suppressing agent comprises, 22-43 pts. wt. tributyltin oxide, 12-20 pts. wt. molybdenum hydroxide, 10-16 pts. wt. kaolin, 6-12 pts. wt. alumina, 8 to 8 pts. wt. ammonium molybdate, 1.2-2 pts. wt. stearic acid. The High toughness graphene modified rubber material produced by (i) crushing the graphene and passing through a 300-500 mesh sieves to obtain a powder, carrying the treatment of obtained powder in a magnetic field strength of 5830-6250GS, ultrasonic power of 350-480 W, temperature of 42-53 degrees C, stirring speed of 200-300 revolutions/minute for 22-36 minutes to obtain graphene energy powder; (ii) adding surfactant into the graphene energy powder prepared in the step (ii), heating at 63-74 degrees C, and rotating speed of 120- 150 revolutions/minute activation 0.9-1.4 hours to obtain the activated graphene energy powder; (iii)adding energy activated graphene powder prepared in the step (ii) to silicone rubber, fluororubber, EVA resin, dibutyl phthalate, glycerol triglyceride, acrylic acid stearate , Maleic anhydride grafting, magnesium hydroxide, kaolin, dolomite powder, calcium hexadecylsulfonate, zinc diethyldithiocarbamate, chlorinated polyethylene, isoprene, polyethylene wax, poly Ethylene phthalate fiber, dimethyl silicone oil, carbon fiber, polyamide fiber, carboxyethyl cellulose, initiator, chain extender, crosslinking agent, leveling agent, catalyst, accelerator, plasticizer, dispersant and tackifier under the protection of nitrogen, treating microwave power of 209-254W, temperature of 125-134 degrees C, stirring speed of 300-500 revolutions/minute under for 3-4.2 hours to obtain the mixture I, and (iv) adding curing agent, an antibacterial agent, an antioxidant, a light stabilizer, a heat stabilizer, an anti-aging agent, an ultraviolet absorber, a flame retardant, and a smoke suppressing agent to the mixture I prepared in step (iii), heating at 64-75 degrees C, stirring AT 100-200 revolutions/minute for 1.3-1.5 hours to obtain the mixture II, where flame retardant, produced by (a) mixing the fatty alcohol polyoxyethylene ether ammonium sulfate, 240-300 pts. wt. water into a microwave reactor and stirring at 400-600 revolutions/minute for 6-10 minutes to obtain a mixture A; (b) adding ethylene glycol ether acetate, benzene-free epoxy resin, tripentaerythritol, urea, alumina, antimony trioxide, manganese oxide, activated clay, penetrant, and synergist to the mixture A, carrying the stirring at 300-500 revolutions/minute, microwave power of 220-250W, heating at 86-93 degrees C, stirring for 2-2.5 hours to obtain the mixture B; (c) cooling the mixture B obtained in step b to room temperature, filtering the precipitate, centrifugal drying at 3000-5000 revolutions/minute until moisture content of less than or equal to 3.4% to obtain flame retardant. The smoke suppressing agent produced by comprises (A) (A) adding mixing tributyltin oxide, molybdenum hydroxide, kaolin, alumina, ammonium heptamolybdate and stearic acid into microwave at power of 200-250W, stirring at 200-400 revolutions/minute at 118 degrees C for 1.3-1.8 hours to obtain a mixture C; (B) cooling the mixture C prepared in step A to room temperature, filtering the precipitate, centrifugal drying at 3000-5000 revolutions/minute until water content less than or equal to 2.8% to obtain smoke suppression agent., and (v) adding mixture II prepared in step (iv) into a double-screw extruder, melting at 224-235 degrees C, stirring at 400-600 revolutions/minute, extruding, bracing by water tank and granulating in the granulator, to obtain high toughness graphene modified rubber material.