• 专利标题:   Preparing graphene oxide-supported diimine-coordinated palladium complex, useful as e.g. catalyst in Suzuki reaction, comprises e.g. reacting aldehyde-containing diimine with silane coupling agent, and then reacting with graphene oxide.
  • 专利号:   CN110302836-A
  • 发明人:   LI T, SUN Y, LIU F
  • 专利权人:   UNIV GUANGDONG PHARMACEUTICAL
  • 国际专利分类:   B01J031/22, C07C001/32, C07C015/14, C07C017/263, C07C201/12, C07C205/06, C07C249/02, C07C025/18, C07C251/08, C07C253/30, C07C255/50, C07C255/54, C07C041/30, C07C043/205, C07C045/68, C07C047/546, C07C047/575, C07C049/782, C07C049/84, C07C067/343, C07C069/78, C07D277/22, C07D277/24, C07D277/30, C07F015/00, C07F007/18
  • 专利详细信息:   CN110302836-A 08 Oct 2019 B01J-031/22 201989 Pages: 20 Chinese
  • 申请详细信息:   CN110302836-A CN10540152 21 Jun 2019
  • 优先权号:   CN10540152

▎ 摘  要

NOVELTY - Preparing graphene oxide-supported diimine-coordinated palladium complex comprises (i) reacting aldehyde-containing diimine (I) with silane coupling agent to obtain silane coupling agent-modified diimine ligand, (ii) reacting silane coupling agent-modified diimine ligand with graphene oxide to obtain graphene oxide-loaded diimine ligand, and (iii) reacting obtained graphene oxide-supported diimine ligand with palladium salt to obtain final product. USE - The product is useful as catalyst in organic synthesis reactions including Suzuki reaction and C-H activation reaction (all claimed). ADVANTAGE - The method produces catalyst that can be recycled many times. DETAILED DESCRIPTION - Preparing graphene oxide-supported diimine-coordinated palladium complex comprises (i) reacting aldehyde-containing diimine of formula (I) with silane coupling agent to obtain silane coupling agent-modified diimine ligand, (ii) reacting silane coupling agent-modified diimine ligand with graphene oxide to obtain graphene oxide-loaded diimine ligand, and (iii) reacting obtained graphene oxide-supported diimine ligand with palladium salt to obtain final product. An INDEPENDENT CLAIM is also included for graphene oxide-supported diimine-coordinated palladium complex obtained by above method.