• 专利标题:   Synthesizing formamide derivative through catalytic formylation reaction of graphene oxide involves reacting diamine compound with formamide compound under catalytic action of graphene oxide.
  • 专利号:   CN107827816-A
  • 发明人:   GONG H, XIE G, CAI C, ZHANG Y
  • 专利权人:   UNIV XIANGTAN
  • 国际专利分类:   C07C231/14, C07C233/03, C07C233/18, C07D209/44, C07D211/16, C07D217/04, C07D295/16, C07D495/04
  • 专利详细信息:   CN107827816-A 23 Mar 2018 C07D-217/04 201827 Pages: 19 Chinese
  • 申请详细信息:   CN107827816-A CN11206076 27 Nov 2017
  • 优先权号:   CN11206076

▎ 摘  要

NOVELTY - The method for synthesizing formamide derivative (II) through catalytic formylation reaction of graphene oxide involves reacting a diamine compound (I) with formamide compound under the catalytic action of graphene oxide to obtain the product, where the reaction is a one-pot reaction. USE - The method is useful for synthesizing compound (II) through catalytic formylation reaction of graphene oxide. ADVANTAGE - The method is capable of simply and economically synthesizing the compound (II) through catalytic formylation reaction of graphene oxide with high selectivity and yield. DETAILED DESCRIPTION - The method for synthesizing formamide derivative of formula: (R1)(R2)N-C(=O)-H (II) through catalytic formylation reaction of graphene oxide involves reacting a diamine compound of formula: R1-NH-R2 (I) with formamide compound under the catalytic action of graphene oxide to obtain the product, where the reaction is a one-pot reaction. R1, R2=H, alkyl, or (hetero)aryl, where R1, R2 are not H at the same time.