• 专利标题:   Preparing boron-doped graphene nanoribbon supported nickel monoatomic catalyst comprises adding multi-walled carbon nanotubes to a strong oxidant, oxidizing at a certain temperature, and obtaining graphene nanoribbons.
  • 专利号:   CN110860291-A
  • 发明人:   GAO X
  • 专利权人:   SEVEN TECHNOLOGY SHANGHAI CO LTD
  • 国际专利分类:   B01J023/755, C25B001/04, C25B011/06
  • 专利详细信息:   CN110860291-A 06 Mar 2020 B01J-023/755 202027 Pages: 8 Chinese
  • 申请详细信息:   CN110860291-A CN11027261 27 Oct 2019
  • 优先权号:   CN11027261

▎ 摘  要

NOVELTY - Preparing boron-doped graphene nanoribbon supported nickel monoatomic catalyst comprises adding multi-walled carbon nanotubes to a strong oxidant, oxidizing at a certain temperature, and obtaining graphene nanoribbons after multiple centrifugal cleaning. The graphene nanoribbons are sonicated, then a boron precursor is added, and boron doping is performed at a high temperature reaction in a hydrothermal kettle to obtain boron-doped graphene nanoribbons. The boron-doped graphene nanoribbons are dissolved in deionized water with stabilizing agent, and the nickel precursor is added under continuous stirring, followed by rapid freeze-drying in liquid nitrogen. The reaction is then heated to a certain temperature under an atmosphere protection reaction, and then annealed at a gas protection temperature, and after the system is naturally cooled to room temperature, washed with anhydrous ethanol multiple times, and vacuum dried to obtain a graphene nanobelt supported nickel single atom. USE - Method for preparing boron-doped graphene nanoribbon supported nickel monoatomic catalyst used for hydrogen production(claimed). ADVANTAGE - The method enables to prepare boron-doped graphene nanoribbon supported nickel monoatomic catalyst, which is suitable for industrial production and has high economic value and has simple preparation process.