• 专利标题:   Preparation of graphene oxide-modified copolyesteramide and its fibers used for electromagnetic and electrostatic protective clothing involves mixing polymerizing caprolactam with graphene oxide, and melt-spinning in twin-screw extruder.
  • 专利号:   CN107385545-A, CN107385545-B
  • 发明人:   HAO C, LAI G, PAN Q, JIANG J, MA Q, LI M, LUO M
  • 专利权人:   UNIV HANGZHOU NORMAL, UNIV HANGZHOU NORMAL
  • 国际专利分类:   C08G069/44, D01D005/08, D01D005/092, D01D005/096, D01D005/16, D01F001/09, D01F001/10, D01F006/92, G21F001/10
  • 专利详细信息:   CN107385545-A 24 Nov 2017 D01F-006/92 201804 Pages: 6 Chinese
  • 申请详细信息:   CN107385545-A CN10496781 26 Jun 2017
  • 优先权号:   CN10496781

▎ 摘  要

NOVELTY - Preparation of graphene oxide-modified copolyesteramide and its fibers comprises mixing graphene oxide and caprolactam monomer, transferring into reaction kettle, adding dicarboxylic acid and ring-opening polymerization catalyst, introducing nitrogen gas, heating mixture to 230-260 degrees C for 4-6 hours, mixing with alcohol oligomer and catalyst, reacting at 230-260 degrees C for 1-3 hours, purging with nitrogen at 230-260 degrees C, cooling, and pelletizing to obtain graphene oxide-modified copolyesteramide chips; and drying chips, and melt-spinning in twin-screw extruder to obtain its fiber. USE - Method for preparing graphene oxide-modified copolyesteramide and its fibers used for electromagnetic and electrostatic protective clothing (claimed). ADVANTAGE - The copolyesteramide has tensile strength of 50-130 MPa, impact strength of 60~140 J/m, conductivity of 10-7-10-2 S/cm, melting temperature of 100-220 degrees C, and moisture rate of 1-6%. DETAILED DESCRIPTION - Preparation of graphene oxide-modified copolyesteramide and its fibers comprises mixing graphene oxide and caprolactam monomer at 121-135 degrees C for 1-3 hours, transferring into reaction kettle, adding dicarboxylic acid and ring-opening polymerization catalyst, introducing nitrogen gas, heating mixture to 230-260 degrees C for 4-6 hours, mixing with alcohol oligomer and catalyst, reacting at 230-260 degrees C for 1-3 hours, purging with nitrogen at 230-260 degrees C, cooling, and pelletizing to obtain graphene oxide-modified copolyesteramide chips; and drying chips, and melt-spinning in twin-screw extruder to obtain its fiber.