▎ 摘 要
NOVELTY - Strong alkaline complex resin material comprises 75-90 wt.% polymerizable monomer, 5-15 wt.% comonomer, 0.1-5 wt.% functionalized graphene and 0.1-10 wt.% initiator. The polymerizable monomer is chloromethylstyrene, 4-(3-chloropropyl)styrene, 4-(3-bromopropyl)styrene, 4-(4-chlorobutyl)styrene, 4-(4-bromobutyl)styrene, 4-(5-chloropentyl)styrene or 4-(5-bromopentyl)styrene. The comonomer is ethylene glycol dimethacrylate, diallyl benzene, divinyl diphenyl methane or divinyl benzene. The functionalized graphene is hydroxylated graphene, carboxylated graphene or amino graphene. USE - Used as a strong alkaline complex resin material. ADVANTAGE - The method is suitable for industrial production of complex resin material. DETAILED DESCRIPTION - Strong alkaline complex resin material comprises 75-90 wt.% polymerizable monomer, 5-15 wt.% comonomer, 0.1-5 wt.% functionalized graphene and 0.1-10 wt.% initiator. The polymerizable monomer is chloromethylstyrene, 4-(3-chloropropyl)styrene, 4-(3-bromopropyl)styrene, 4-(4-chlorobutyl)styrene, 4-(4-bromobutyl)styrene, 4-(5-chloropentyl)styrene or 4-(5-bromopentyl)styrene. The comonomer is ethylene glycol dimethacrylate, diallyl benzene, divinyl diphenyl methane or divinyl benzene. The functionalized graphene is hydroxylated graphene, carboxylated graphene or amino graphene. The initiator is benzoyl peroxide, azobisisobutyronitrile, lauroyl peroxide or cumene hydroperoxide. An INDEPENDENT CLAIM is also included for preparing strong alkaline complex resin material comprises: (i) mixing polymerizable monomer, co-monomers, functionalized graphene and initiator to obtain a solution-A; (ii) subjecting the solution-A to ultrasonic oscillation treatment at 20-50 degrees C for 8-20 minutes with a power of 40-100 W and a frequency of 30-100 kHz to obtain solution-B; (iii) preparing 0.5-5 wt.% polymeric additive aqueous solution as solution-C, where the polymeric additive is polyvinyl alcohol, gelatin, starch, methyl cellulose, bentonite and calcium carbonate, the amount of polymeric additive is 5-50 wt.% to the amount of polymerizable monomer; and (iv) pre-polymerizing the solution-B at 60-75 degrees C for 0.5-2.5 hours, mixing the solution-B with solution-C, reacting at 70-90 degrees C for 5-15 hours, then curing at 90-100 degrees C for 5-15 hours, decanting the supernatant, washing, filtering, drying and sieving to obtain complex resin microspheres having a particle size of 0.35-0.60 mm; and (v) adding 110-250 wt.% swelling agent into complex resin microspheres, then adding 70-200% amination reagent and 60-180% alkali, reacting at 25-45 degrees C for 5-30 hours, washing, adding transformation agent for transformation, then washing to neutrality with water, where the swelling agent is dichloromethane, 1,2-dichloroethane, trichloromethane or tetrahydrofuran, the amination reagent is trimethylamine salt, triethylamine salt, diethylamine salt or tributyl salt, the alkali is sodium hydroxide or potassium hydroxide, the transformation agent is sodium hydroxide, sodium bicarbonate, sodium formate or sodium acetate.