• 专利标题:   Graphene oxide/polyvinylidene fluoride blended cation exchange membrane comprises polyvinylidene fluoride, graphene oxide, organic solvent, divinylbenzene, glycidyl methacrylate and benzoyl peroxide.
  • 专利号:   CN103087342-A, CN103087342-B
  • 发明人:   LIANG S, TANG Y
  • 专利权人:   UNIV TONGJI
  • 国际专利分类:   B01D067/00, B01D069/02, B01D071/34, C08J005/18, C08J007/16, C08K003/04, C08K007/00, C08L027/16
  • 专利详细信息:   CN103087342-A 08 May 2013 C08J-007/16 201401 Pages: 12 Chinese
  • 申请详细信息:   CN103087342-A CN10023723 22 Jan 2013
  • 优先权号:   CN10023723

▎ 摘  要

NOVELTY - A graphene oxide/polyvinylidene fluoride (PVDF) blended cation exchange membrane comprises 5-20 wt.% polyvinylidene fluoride, 0.1-5 wt.% graphene oxide, 50-70 organic solvent, 10-20 wt.% divinylbenzene, 6-20 wt.% glycidyl methacrylate and 0.5-5 wt.% benzoyl peroxide. USE - Graphene oxide/polyvinylidene fluoride (PVDF) blended cation exchange membrane. ADVANTAGE - The blended cation exchange membrane retains excellent characteristics of PVDF cation exchange membranes, has enhanced surface properties, hydrophilicity, mechanical strength and acid alkali resistances, and has improved anti-pollution capacity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the graphene oxide/PVDF blend cation-exchange membrane which comprises: (A) providing above raw materials; (B) dissolving graphene oxide in organic solvent and performing ultrasonic dispersion; (C) dissolving polyvinylidene fluoride in organic solvent and performing ultrasonic dispersion; (D) mixing above resulting solutions with divinylbenzene, glycidyl methacrylate and benzoyl peroxide, performing ultrasonic dispersion, standing and defoaming to yield casting solution; (E) casting film solution on glass plate film; (F) drying resulting film from glass plate and obtaining base film; and (G) passing base film through different concentration of concentrated sulfuric acid and deionized water; and immersing base film into collapse sodium hydroxide solution, washing with deionized water to obtain graphene oxide/PVDF blend cation exchange membrane.