• 专利标题:   Preparation method of pyrrole nitrogen doped graphene, involves cooling solid reaction product, taking out, stirring and soaking in hydrochloric acid, and using pure water to wash until pH is higher to obtain black nitrogen-doped graphene.
  • 专利号:   CN115285979-A
  • 发明人:   CAO G, MING H, XIANG Y, LAI R, ZHANG H, ZHANG W
  • 专利权人:   PLA ACAD MILITARY SCI CHEM DEFENSE INST
  • 国际专利分类:   C01B032/184, C01B032/194
  • 专利详细信息:   CN115285979-A 04 Nov 2022 C01B-032/184 202307 Chinese
  • 申请详细信息:   CN115285979-A CN10903682 29 Jul 2022
  • 优先权号:   CN10903682

▎ 摘  要

NOVELTY - The method involves uniformly mixing 2.4 g metal magnesium powder and magnesium sulfate or magnesium oxide in a mass ratio of 1:5-20, placing in a vacuum reactor with a vacuum degree of 500-1000 Pa, heating to 900-1300 degree Celsius, quickly placing 1.26-6.3 g melamine into the pyrolysis reactor preheated to 900 to 1500 degree Celsius to make it finish cracking in 10-150 seconds, and directly introducing the mixed gas of melamine pyrosis product gas and carrier gas into the vacuum reactor. USE - Preparation method of pyrrole nitrogen doped graphene. ADVANTAGE - The method ensures the uniqueness of nitrogen atom configuration in the graphene. The nitrogen source precursor can quickly enter into the high temperature environment to be heated, the device requirement is low, the process is simple, and it is easy to realize large-scale production. The method provides the nitrogen atom in the nitrogen-doped graphene only exists in the pyrrole configuration, which can be widely used for catalyzing, super capacitor, and lithium battery and has excellent application performance. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic representation of mass spectrometric analysis results of the melamine cleavage process.