• 专利标题:   Preparing graphene-doped polyimide powder used e.g. in lost foam casting, comprises e.g. mixing and reacting graphene with organic solvent, diamine and dianhydride by in-situ polymerization, adding e.g. catalyst, performing chemical imidization of polyamic acid, and grinding polyimide product.
  • 专利号:   CN115819763-A
  • 发明人:   MIN Y, QIU W, LUO X, LIU Y
  • 专利权人:   HUIMAI MATERIALS TECHNOLOGY GUANGDONG CO
  • 国际专利分类:   C08G073/10, C08K003/04
  • 专利详细信息:   CN115819763-A 21 Mar 2023 C08G-073/10 202330 Chinese
  • 申请详细信息:   CN115819763-A CN11288954 20 Oct 2022
  • 优先权号:   CN11288954

▎ 摘  要

NOVELTY - Preparing graphene-doped polyimide powder, comprises: (i) using in-situ polymerization for mixing and reacting graphene with organic solvent, diamine and dianhydride in a reaction vessel to obtain graphene-based polyamic acid; (ii) adding catalyst and dehydrating agent to a polytetrafluoroethylene reaction vessel, stirring and reacting for chemical imidization of polyamic acid to produce polyimide; (iii) removing out polyimide product, washing and soaking with acetone for a period of time, and then placing in a vacuum drying oven for drying; and (iv) grinding using a grinder to obtain the final product. USE - The method is useful for preparing graphene-doped polyimide powder used in lost foam casting, selective laser sintering (SLS) molding, and graphite powder preparation. ADVANTAGE - The method is simple to operate, has mild reaction conditions and high production efficiency, does not require high temperature conditions, saves energy, and easily achieves industrial production. DESCRIPTION OF DRAWING(S) - The drawing shows graphene (GN)/polyimide (PI) composite powder of different gradients.