• 专利标题:   Catalyst, comprises cobalt nitrate hexahydrate, nitrogen-doped graphene, potassium borohydride and palladium chloride solution in specific weight parts.
  • 专利号:   CN105977504-A
  • 发明人:   ZHENG Y
  • 专利权人:   ZHENG Y
  • 国际专利分类:   H01M004/88, H01M004/90, H01M004/92
  • 专利详细信息:   CN105977504-A 28 Sep 2016 H01M-004/92 201676 Pages: 15 Chinese
  • 申请详细信息:   CN105977504-A CN10576659 18 Jul 2016
  • 优先权号:   CN10576659

▎ 摘  要

NOVELTY - A catalyst comprises 100 pts. wt. cobalt nitrate hexahydrate, 200-250 pts. wt. nitrogen-doped graphene, 1175-1250 pts. wt. potassium borohydride and 0.05 mol/l palladium chloride solution, where molar ratio of palladium and cobalt is 2:1-4. USE - Catalyst. ADVANTAGE - The catalyst promotes oxygen species desorption and dispersion of palladium-cobalt alloy with nitrogen-doped graphene, distributes palladium particles uniformly on uniformly sized carrier, enhances catalytic oxygen reduction catalyst and improves performance and stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a method for manufacturing a catalyst, which involves adding proper amount of deionized water to nitrogen-doped graphene, dissolving potassium borohydride in deionized water, adding cobalt nitrate hexahydrate and palladium chloride into the mixed solution of nitrogen-doped graphene, dispersing the mixture ultrasonically for 5-15 minutes, introducing nitrogen into the mixture to remove oxygen, condensing the mixture at 50-60 degrees C, injecting potassium borohydride solution to the obtained mixture at a rate of 1 drops/second, reacting the mixture for 5.5-6.5 hours, filtering hot mixture and washing impurities with deionized water at 60-75 degrees C to obtain finished product, where mass ratio of nitrogen-doped graphene and deionized water is 1:450-550 and mass ratio of potassium borohydride and deionized water is 1:180-200.