• 专利标题:   Preparation of composite nanomaterial for modified forward osmosis nanocomposite membrane, involves dissolving sulfonated graphene oxide in dimethylformamide, adding zirconium chloride and terephthalic acid, and ultrasonically-processing.
  • 专利号:   CN112210081-A, CN112210081-B
  • 发明人:   WANG L, HE M, ZHANG Y, MIAO R, ZHU J
  • 专利权人:   UNIV XIAN ARCHITECTURE TECHNOLOGY
  • 国际专利分类:   B01D067/00, B01D069/12, B01D071/76, C08G083/00, C08K003/04
  • 专利详细信息:   CN112210081-A 12 Jan 2021 C08G-083/00 202114 Pages: 10 Chinese
  • 申请详细信息:   CN112210081-A CN11057319 29 Sep 2020
  • 优先权号:   CN11057319

▎ 摘  要

NOVELTY - Preparation of sulfonated graphene oxide-supported metal organic framework composite nanomaterial involves dissolving sulfonated graphene oxide in dimethylformamide at room temperature, ultrasonically-processing (p1), adding zirconium chloride and terephthalic acid in a molar ratio of 1:(1-2), ultrasonically-processing (p2), adding concentrated hydrochloric acid to obtain a mixed solution, maintaining at 80-180 degrees C, and reacting for 36-48 hours. The mass ratio of sulfonated graphene oxide with respect to total amount of terephthalic acid and zirconium chloride is 0-0.15. USE - Preparation of composite nanomaterial used for preparing sulfonated graphene oxide-supported metal organic framework modified forward osmosis nanocomposite membrane (all claimed). ADVANTAGE - The method enables preparation of sulfonated graphene oxide-supported metal organic framework composite nanomaterial having improved membrane salt cut-off performance and pollution removal performance by suppressing agglomeration of nanomaterial. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the sulfonated graphene oxide-supported metal organic framework modified forward osmosis nanocomposite membrane, which involves dissolving (i) m-phenylenediamine in deionized water to obtain an aqueous monomer solution, dissolving trimesoyl chloride in n-hexane to obtain an organic phase solution, adding the sulfonated graphene oxide-supported metal organic framework composite nanomaterial to the organic phase solution, and ultrasonically-dispersing to obtain a treated organic phase solution, and immersing (ii) a base film in the aqueous monomer solution, drying to remove excess liquid to obtain a dried film, applying the treated organic phase solution to surface of dried film, performing interfacial polymerization reaction to obtain a separation layer.