• 专利标题:   Method for preparing cathode material that is utilized for manufacturing lithium ion battery, involves adding graphene powder in mixed solution of sulfuric acid and nitric acid, stirring mixture, and treating with carboxyl functional group.
  • 专利号:   CN102646821-A, CN102646821-B
  • 发明人:   CHEN Y, HUANG R, HE J, LI P, LI Y, WANG Z, ZHANG W
  • 专利权人:   UNIV CHINA ELECTRONIC SCI TECHNOLOGY
  • 国际专利分类:   H01M004/38
  • 专利详细信息:   CN102646821-A 22 Aug 2012 H01M-004/38 201322 Pages: 8 Chinese
  • 申请详细信息:   CN102646821-A CN10138679 08 May 2012
  • 优先权号:   CN10138679

▎ 摘  要

NOVELTY - A cathode material preparing method involves adding graphene powder in mixed solution of concentrated sulfuric acid and concentrated nitric acid at 50-100 degrees C, stirring for 1-10 hours, standing for 10-20 hours, cleaning with deionized water till the solution is neutral and ultrasonically treating for 1-4 hours with carboxyl functional group. The resultant product is added to a mixture containing 0.5-2 mass parts of magnesium chloride and water, followed by adding carrying carboxyl functional group, and dispersing ultrasonically to obtain magnesium chloride with carboxyl functional group. USE - Method for preparing cathode material that is utilized for manufacturing a lithium ion battery. DETAILED DESCRIPTION - A cathode material preparing method involves adding graphene powder in mixed solution of concentrated sulfuric acid and concentrated nitric acid at 50-100 degrees C, stirring for 1-10 hours, standing for 10-20 hours, cleaning with deionized water till the solution is neutral and ultrasonically treating for 1-4 hours with carboxyl functional group. The resultant product is added to a mixture containing 0.5-2 mass parts of magnesium chloride and water, followed by adding carrying carboxyl functional group, dispersing ultrasonically to obtain magnesium chloride with carboxyl functional group, evaporating solvent material, treating at 800-1200 degrees C, stirring mixture and sealing in a cavity. The resultant product is vacuumized, followed by treating at a vacuum degree of 150 Pa under mixed gas of argon gas and hydrogen in a volume ratio of 3:6 at 500-1000 degrees C for 5-20 minutes, stopping inletting carbon-containing gas, maintaining resultant product under argon gas and hydrogen atmosphere for 1-6 hours and cooling to room temperature under the protection of the argon gas to obtain a finished product.