• 专利标题:   Reduction of graphene oxide used for preparing lithium ion battery anode and cathode material, includes weighing graphite powder and sodium nitrate, homogenizing, adding concentrated sulfuric acid, cooling and adding potassium permanganate.
  • 专利号:   CN104617300-A
  • 发明人:   LI D, LI X, XIONG D, DONG L, SHAN H
  • 专利权人:   UNIV TIANJIN NORMAL
  • 国际专利分类:   C01B031/04, H01M010/0525, H01M004/587
  • 专利详细信息:   CN104617300-A 13 May 2015 H01M-004/587 201556 Pages: 12 Chinese
  • 申请详细信息:   CN104617300-A CN10065085 09 Feb 2015
  • 优先权号:   CN10065085

▎ 摘  要

NOVELTY - Reduction of graphene oxide includes weighing 0.1-5 g graphite powder and 0.05-5 g sodium nitrate, homogenizing, adding concentrated sulfuric acid, cooling under ice bath, adding 0.5-20 g potassium permanganate, stirring for 0.5-5 hours, standing for 1-5 days at room temperature, adding 10-500 mL 1-10% sulfuric acid, stirring for 0.5-5 hours, adding 0.5-20 mL hydrogen peroxide solution until bubbles disappear, washing with 5-10% nitric acid and 1-5% nitric acid, adding deionized water, centrifuging, drying at 25 degrees C and performing ultrasonic dispersion in water/organic solvent. USE - Method for reducing graphene oxide used for preparing lithium ion battery anode and cathode material (claimed). ADVANTAGE - The method has high stability, inexpensive, and has simple preparation. DETAILED DESCRIPTION - Reduction of graphene oxide involves weighing 0.1-5 g graphite powder and 0.05-5 g sodium nitrate, homogenizing, adding concentrated sulfuric acid, cooling under ice bath, adding 0.5-20 g potassium permanganate, stirring for 0.5-5 hours, standing for 1-5 days at room temperature, adding 10-500 mL 1-10% sulfuric acid, stirring for 0.5-5 hours, adding 0.5-20 mL hydrogen peroxide solution until bubbles disappear, washing with 5-10% nitric acid and 1-5% nitric acid, adding deionized water, centrifuging, drying at 25 degrees C, performing ultrasonic dispersion in water/organic solvent, adding reducing agent, performing reduction under oil bath and freeze-drying.