• 专利标题:   Dispersion of nanoparticles of graphene in water in presence of surfactant, used for treating articles of manufacture, and used as additive or component of elastomeric compositions or of paints or of textile articles.
  • 专利号:   WO2014135455-A1, IT1416461-B, CN105073636-A, US2015376014-A1, EP2964575-A1, CN105073636-B, US10435837-B2, EP2964575-B1
  • 发明人:   CESAREO G, PARRINI M R, RIZZI L G, PARRINI R
  • 专利权人:   DIRECTA PLUS SPA, DIRECTA PLUS SPA, DIRECTA PLUS SPA, DIRECTA PLUS SPA, DIRECTA PLUS SPA
  • 国际专利分类:   C01B031/04, C01B000/00, C08K003/04, C09D007/12, D06M011/74, C01B032/19, C01B032/225, B82Y030/00, B82Y040/00, C01B032/194, C09D007/61
  • 专利详细信息:   WO2014135455-A1 12 Sep 2014 C01B-031/04 201461 Pages: 15 English
  • 申请详细信息:   WO2014135455-A1 WOEP053966 28 Feb 2014
  • 优先权号:   ITMI0334

▎ 摘  要

NOVELTY - Dispersion of nanoparticles of graphene in water in the presence of a surfactant, where concentration of nanoparticles of graphene in water is from 5% to 50 wt.%; the carbon/oxygen (C/O) ratio in nanoparticles of graphene is greater than or equal to 100:1; at least 90% of the nanoparticles of graphene have a lateral size (x, y) from 1 0 to 10,000 nm, and a thickness (z) from 0.34 to 30 nm, the lateral size being always greater than thickness (x, y not greater than z). The surfactant is present in amount from 1 to 20 wt.% with respect to weight of the graphene and is anionic surfactant or nonionic surfactant or its mixture. USE - The dispersion of nanoparticles of graphene is useful for treating articles of manufacture; and useful as additive or component of elastomeric compositions or of paints or of textile articles (claimed). ADVANTAGE - Dispersion of graphene is provided in relatively concentrated form, produced with a liquid medium that is readily available, inexpensive and very safe from a health and environmental perspective. Safe and reliable process is also provide for preparing dispersion of graphene that enables graphene to be obtained in a very pure form and with a minimum amount of iodized product. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a process for producing a dispersion of nanoparticles of graphene in water, which involves the expansion of flakes of intercalated graphite having a lateral size of less than or equal to 500 mu m by exposure to a temperature of at least 1300 degrees C for a time of less than 1 second, where: (a) the expanded graphite so obtained is dispersed in water at a concentration from 5% to 50 wt.%, in the presence of a surfactant in an amount from 1 to 20 wt.% with respect to the weight of the graphite, the surfactant being an anionic surfactant or a nonionic surfactant or its mixture; and (b) the water dispersion obtained from step (a) is treated with ultrasounds at an energy level from 100 to 2000 W for a period of from 1 to 100 hours.