• 专利标题:   Preparation of graphene oxide grafted polyvinylidene fluoride by adding graphene oxide in solvent, ultrasonically dispersing ice water bath, under stirring condition, and adding carboxyl xanthate, catalyst and water reducing agent.
  • 专利号:   CN108557812-A
  • 发明人:   XU L, ZHANG L, ZHANG S, ZONG C, ZHANG Y, DI C, ZHU Z
  • 专利权人:   UNIV JINAN
  • 国际专利分类:   C01B032/198, C08F114/22, C08F002/38
  • 专利详细信息:   CN108557812-A 21 Sep 2018 C01B-032/198 201876 Pages: 11 Chinese
  • 申请详细信息:   CN108557812-A CN10270709 29 Mar 2018
  • 优先权号:   CN10270709

▎ 摘  要

NOVELTY - Preparation of graphene oxide grafted polyvinylidene fluoride comprises preparing graphene oxide by Hummer's method, adding in solvent A, ultrasonically dispersing under ice water bath, under stirring condition, sequentially adding carboxyl xanthate, catalyst and water reducing agent, reacting at room temperature, filtering, vacuum drying to obtain surface-modified graphene oxide, adding in solvent B, ultrasonically dispersing, transferring into a reaction kettle, adding initiator and vinylidene fluoride gas monomer, stirring under heating condition for reversible-addition-fragmentation chain transfer polymerization, and after finishing the reaction, drying. USE - Preparation of graphene oxide grafted polyvinylidene fluoride. ADVANTAGE - The method greatly improves the grafting rate, has simple preparation technique, is suitable for industrial production, and provides product with high tensile strength, good thermal stability and high mechanical strength.