• 专利标题:   Preparation of ionic liquid modified graphene composite polyaniline hollow microsphere by dispersing graphene oxide in water, forming graphene oxide water dispersion, adding ionic liquid catalyst, and performing modification reaction.
  • 专利号:   CN112980184-A, CN112980184-B
  • 发明人:   LUO J, WANG Y
  • 专利权人:   UNIV JIANGNAN
  • 国际专利分类:   C08K003/04, C08K009/04, C08L079/02
  • 专利详细信息:   CN112980184-A 18 Jun 2021 C08L-079/02 202168 Pages: 9 Chinese
  • 申请详细信息:   CN112980184-A CN10214200 26 Feb 2021
  • 优先权号:   CN10214200

▎ 摘  要

NOVELTY - Preparation of ionic liquid modified graphene composite polyaniline hollow microsphere comprises preparing ionic liquid modified reduced graphene oxide by dispersing graphene oxide in water, forming graphene oxide water dispersion, adding ionic liquid catalyst, performing modification reaction to obtain graphene oxide modified by ionic liquid, adding reducing agent, carrying out reduction reaction, filtering, and washing to obtain ionic liquid modified reduced graphene oxide (rGO-IL); preparing oil-in-water Pickering emulsion by dispersing the rGO-IL in water, forming rGO-IL water dispersion liquid as water phase, using organic solvent containing aniline monomer as oil phase, and mixing the two, and using homogenizer to emulsify and obtain oil-in-water type Pickering emulsion; and preparing hollow microsphere by putting the emulsion in ice water bath, gradually adding ammonium persulfate hydrochloric acid solution under the same ice bath, and reacting in ice water bath. USE - The method is for preparation of ionic liquid modified graphene composite polyaniline hollow microsphere. ADVANTAGE - The method is simple and mild. DETAILED DESCRIPTION - Preparation of ionic liquid modified graphene composite polyaniline hollow microsphere comprises preparing ionic liquid modified reduced graphene oxide by dispersing graphene oxide in water, forming graphene oxide water dispersion, adding ionic liquid catalyst, performing modification reaction to obtain graphene oxide modified by ionic liquid, adding reducing agent, carrying out reduction reaction, filtering, and washing to obtain rGO-IL; preparing oil-in-water Pickering emulsion by dispersing the rGO-IL in water, forming rGO-IL water dispersion liquid as water phase, using organic solvent containing aniline monomer as oil phase, and mixing the two, and using homogenizer to emulsify and obtain oil-in-water type Pickering emulsion; and preparing hollow microsphere by putting the emulsion in ice water bath for 20-60 minutes, gradually adding ammonium persulfate hydrochloric acid solution under the same ice bath, reacting in ice water bath for 20-28 hours, washing and freeze drying the product i.e. hollow microsphere rGO-IL/PANIHS.