• 专利标题:   Nanoporous graphene structure for sieving, sensing molecular species, and electronic transport used in field-effect transistor-sensor device and gate-controlled sieve mesh, comprises monolithically-integrated parallel arrays of nanoribbons.
  • 专利号:   WO2019158694-A1
  • 发明人:   MORENO SIERRA C, MUGARZA EZPELETA A, CEBALLOS MAGO G A, PENA GIL D, VILAS VARELA M
  • 专利权人:   FUNDACIO INST CATALA NANOCIENCIA I NANOT, CATALANA RECERCA ESTUDIS AVANCATS INST, UNIV SANTIAGO COMPOSTELA
  • 国际专利分类:   C01B032/184, C07D215/00
  • 专利详细信息:   WO2019158694-A1 22 Aug 2019 C01B-032/184 201971 Pages: 56 English
  • 申请详细信息:   WO2019158694-A1 WOEP053816 15 Feb 2019
  • 优先权号:   EP382088

▎ 摘  要

NOVELTY - Nanoporous graphene structure comprises monolithically-integrated parallel arrays of nanoribbons and atomically precise nanopores, where the nanoribbons are parallel interconnected with identical interconnections between two neighboring nanoribbons to form nanopores with atomic precision and periodic replication between two neighboring interconnections, and the nanoporous graphene structure has one-dimensional conducting channels. USE - Nanoporous graphene structure for sieving, sensing molecular species, and/or for electronic transport used in FET-sensor device and gate-controlled sieve mesh (all claimed). ADVANTAGE - The nanoporous graphene structure exhibits simultaneous semiconducting and nanosieving functionalities and electronic properties, has atomic scale structural uniformity, which appear randomly distributed on the catalytic surface, with seldom accidental interconnections. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method preparing a nanoporous graphene structure, which involves providing at least one NPG precursor, which has a substituted or unsubstituted polycyclic aromatic compound with n aryl groups and two or more halide leaving groups on a solid substrate, polymerizing the NPG precursors to form at least one polymer on the surface of the solid substrate, performing at least partial cylcodehydrogenation of one or more polymers to convert the polymers into graphene nanoribbons, performing at least partial covalent cross coupling of two or more graphene nanoribbons formed to laterally interconnect the graphene nanoribbons for forming nanoporous in the graphene structure and optionally, transferring the nanoporous graphene structure to other solid or liquid environment.